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  • Microcolumn liquid chromatography  (1)
  • impact‐based forecasting  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 11 (1988), S. 858-861 
    ISSN: 0935-6304
    Keywords: Microcolumn liquid chromatography ; Solvent modulation ; Mobile-phase gradient programming ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An innovative solvent delivery method termed solvent modulation has been developed to control solute retention in liquid chromatography. Solvent modulation is the technique whereby individual solvent zones are introduced onto the chromatographic column in a known random orrepeating sequence. Because the solvent zones are of constant composition and are spatially separated from one another, solute retention is controlled independently in each zone. Hence, the overall retention of a solute is a time-weighted average of the capacity factors in the solvent zones it has encountered. Solvent modulation offers a simple, versatile, and accurately modeled means to control and predict solute retention in liquid chromatography.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2021-07-21
    Description: Pluvial floods in urban areas are caused by local, fast storm events with very high rainfall rates, which lead to inundation of streets and buildings before the storm water reaches a watercourse. An increase in frequency and intensity of heavy rainfall events and an ongoing urbanization may further increase the risk of pluvial flooding in many urban areas. Currently, warnings for pluvial floods are mostly limited to information on rainfall intensities and durations over larger areas, which is often not detailed enough to effectively protect people and goods. We present a proof‐of‐concept for an impact‐based forecasting system for pluvial floods. Using a model chain consisting of a rainfall forecast, an inundation, a contaminant transport and a damage model, we are able to provide predictions for the expected rainfall, the inundated areas, spreading of potential contamination and the expected damage to residential buildings. We use a neural network‐based inundation model, which significantly reduces the computation time of the model chain. To demonstrate the feasibility, we perform a hindcast of a recent pluvial flood event in an urban area in Germany. The required spatio‐temporal accuracy of rainfall forecasts is still a major challenge, but our results show that reliable impact‐based warnings can be forecasts are available up to 5 min before the peak of an extreme rainfall event. Based on our results, we discuss how the outputs of the impact‐based forecast could be used to disseminate impact‐based early warnings.
    Description: Plain Language Summary: Pluvial floods are caused by local rain storms with extreme rainfall rates, which leads to immediate flooding of streets and buildings in urban areas. These events are expected to increase in the future due to climate change and growing urban areas. Pluvial floods are directly caused by a rainstorm, which gives citizens and emergency responders usually only a few minutes to act. Existing forecasting systems for pluvial floods are limited to rainfall forecasts that neither provide information about where a flood might occur nor how severe the impacts will be. Here, the main challenge is that current computer models that predict inundation take too long to run to release flood forecasts early enough. We present a new inundation model that can predict inundation for an upcoming flood event in a fraction of the time of existing models. We combine this model with models that predict the spreading of contamination (e.g., from a car accident) and the damage to residential buildings. For a real flood event we can show that this information can be released up to 5 min before the rainfall peak, which gives citizens and emergency responders the opportunities to safe lives and protect important valuables.
    Description: Key Points: First impact‐based forecasting for pluvial foods. Artificial neural network inundation model significantly cuts calculation time to 0.1% of a physically based model with comparable accuracy. Forecast with estimates for inundated areas, spreading of contaminants and expected damage could be released 5 min before peak rainfall.
    Description: Bundesministerium für Bildung und Forschung (BMBF)
    Description: Z Zurich Foundation
    Description: Grantham Foundation for the Protection of the Environment
    Description: ESRC Centre for Climate Change Economics and Policy: ES/R009708/1
    Keywords: 551.489 ; early warning ; impact‐based forecasting ; pluvial floods
    Type: article
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