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  • Mg/Ca  (2)
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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 21 (2006): PA1014, doi:10.1029/2005PA001162.
    Description: Sea surface temperature (SST) and seawater δ18O (δ18Ow) were reconstructed in a suite of sediment cores from throughout the Arabian Sea for four distinct time intervals (0 ka, 8 ka, 15 ka, and 20 ka) with the aim of understanding the history of the Indian Monsoon and the climate of the Arabian Sea region. This was accomplished through the use of paired Mg/Ca and δ18O measurements of the planktonic foraminifer Globigerinoides ruber. By analyzing basin-wide changes and changes in cross-basinal gradients, we assess both monsoonal and regional-scale climate changes. SST was colder than present for the majority of sites within all three paleotime slices. Furthermore, both the Indian Monsoon and the regional Arabian Sea mean climate have varied substantially over the past 20 kyr. The 20 ka and 15 ka time slices exhibit average negative temperature anomalies of 2.5°–3.5°C attributable, in part, to the influences of glacial atmospheric CO2 concentrations and large continental ice sheets. The elimination of the cross-basinal SST gradient during these two time slices likely reflects a decrease in summer monsoon and an increase in winter monsoon strength. Changes in δ18Ow that are smaller than the δ18O signal due to global ice volume reflect decreased evaporation and increased winter monsoon mixing. SSTs throughout the Arabian Sea were still cooler than present by an average of 1.4°C in the 8 ka time slice. These cool SSTs, along with lower δ18Ow throughout the basin, are attributed to stronger than modern summer and winter monsoons and increased runoff and precipitation. The results of this study underscore the importance of taking a spatial approach to the reconstruction of processes such as monsoon upwelling.
    Description: Analyses were funded by a SGER grant from the NSF (OCE03–34598). Funding was also provided by a Schlanger Ocean Drilling Program Fellowship (to K.A.D.) and NSF Grant OCE02–20776 (to D.W.O.). 16
    Keywords: Arabian Sea ; Mg/Ca ; Indian monsoon
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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  • 2
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 6 (2005): Q12P07, doi:10.1029/2005GC000974.
    Description: Secondary ion mass spectrometry (SIMS) is useful for measuring Mg/Ca in both primary calcite and diagenetic minerals in planktonic foraminifera. The excellent spatial resolution (〈10 μm) and small amount of material removed (〈2 ng) makes it easy to avoid targets that include obvious embedding material and encrusting or infilling minerals such as secondary calcite and authigenic clays in diagenetically altered samples. Because analyses can be performed on individuals, SIMS is also a viable technique for generating Mg/Ca values from sediment samples in which foraminifera are rare or have low mass. For clean primary calcite samples, Mg/Ca ratios from SIMS compare well to those obtained using inductively coupled plasma mass spectrometry (ICP-MS), while maintaining information regarding the true variability of elemental ratios within individual tests. For samples with secondary calcite or stubbornly adhering clays, SIMS enables us to accurately measure primary calcite compositions and to assess and reconcile contamination problems in bulk samples analyzed by solution-based ICP-MS. We have observed that SIMS is an invaluable and reliable tool for the identification and avoidance of problems of diagenesis and the analysis of rare or delicate planktonic foraminifera. However, because of operator time required to properly target delicate (thin-walled) or contaminated planktonic foraminifera, SIMS may not be feasible for Mg/Ca studies where large numbers (hundreds) of samples must be processed and bulk measurements on multiple individuals will suffice.
    Description: Funding for this research was provided by The Andrew W. Mellon Foundation Endowed Fund for Innovative Research and by the U.S. Science Support Program of the Joint Oceanographic Institutions. This material is also based on work supported by the National Science Foundation under grant OCE-0334598. Partial support for the Northeast National Ion Microprobe Facility was provided by NSF (EAR-0115433). This research used samples and data provided by the Ocean Drilling Program (ODP). ODP is sponsored by the U.S. National Science Foundation and participating countries under management of Joint Oceanographic Institutions, Inc.
    Keywords: Cenomanian ; Eocene ; Holocene ; Mg/Ca ; Paleoceanography ; Paleocene
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: 539255 bytes
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