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  • Mg/Ca
  • Opal flux
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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2013. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Geochimica et Cosmochimica Acta 121 (2013):196-213, doi:10.1016/j.gca.2013.07.028.
    Description: The Mg/Ca ratio in foraminiferal calcite is one of the principal proxies used for paleoceanographic temperature reconstructions, but recent core-top sediment observations suggest that salinity may exert a significant secondary control on planktic foraminifers. This study compiles new and published laboratory culture experiment data from the planktic foraminifers Orbulina universa, Globigerinoides sacculifer and Globigerinoides ruber, in which salinity was varied but temperature, pH and light were held constant. Combining new data with results from previous culture studies yields a Mg/Ca-sensitivity to salinity of 4.4±2.3%, 4.7±1.2%, and 3.3±1.7% per salinity unit (95% confidence), respectively, for the three foraminifer species studied here. Comparison of these sensitivities with core-top data suggests that the much larger sensitivity (27±4% per salinity unit) derived from Atlantic core-top sediments in previous studies is not a direct effect of salinity. Rather, we suggest that the dissolution correction often applied to Mg/Ca data can lead to significant overestimation of temperatures. We are able to reconcile culture calibrations with core-top observations by combining evidence for seasonal occurrence and latitude-specific habitat depth preferences with corresponding variations in physico-chemical environmental parameters. Although both Mg/Ca and δ18O yield temperature estimates that fall within the bounds of hydrographic observations, discrepancies between the two proxies highlight unresolved challenges with the use of paired Mg/Ca and δ18O analyses to reconstruct paleo-salinity patterns across ocean basins. The first step towards resolving these challenges requires a better spatially and seasonally resolved δ18Osw archive than is currently available. Nonetheless, site-specific reconstructions of salinity change through time may be valid.
    Description: This research was supported by NSF OCE 07-51764 (BH), OCE 05-50703 (HJS), ARC DP 8800010 (SE), OCE 07-52649 (PdeM), ERC 2010-NEWLOG ADG-267931 (HE) and a Columbia Climate Center Grant (KA and BH).
    Keywords: Sea surface temperatures ; Mg/Ca ; δ18O ; Planktic foraminifers ; Salinity
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
    Format: application/pdf
    Format: application/vnd.ms-excel
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  • 2
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 31 (2016): 185–202, doi:10.1002/2015PA002862.
    Description: The intertropical convergence zone and the African monsoon system are highly sensitive to climate forcing at orbital and millennial timescales. Both systems influence the strength and direction of the trade winds along northwest Africa and thus directly impact coastal upwelling. Sediment cores from the northwest African margin record upwelling-related changes in biological productivity connected to changes in regional and hemispheric climate. We present records of 230Th-normalized biogenic opal and Corg fluxes using a meridional transect of four cores from 19°N–31°N along the northwest African margin to examine changes in paleoproductivity since the last glacial maximum. We find large changes in biogenic fluxes synchronous with changes in eolian fluxes calculated using end-member modeling, suggesting that paleoproductivity and dust fluxes were strongly coupled, likely linked by changes in wind strength. Opal and Corg fluxes increase at all sites during Heinrich Stadial 1 and the Younger Dryas, consistent with an overall intensification of the trade winds, and changes in the meridional flux gradient indicate a southward wind shift at these times. Biogenic fluxes were lowest, and the meridional flux gradients were weakest during the African Humid Period when the monsoon was invigorated due to precessional changes, with greater rainfall and weaker trade winds over northwest Africa. These results expand the spatial coverage of previous paleoproxy studies showing similar changes, and they provide support for modeling studies showing changes in wind strength and direction consistent with increased upwelling during abrupt coolings and decreased upwelling during the African Humid Period.
    Description: NSF Grant Numbers: OCE-1103262, OCE-1030784, OCE-0402348; Center for Climate and Life
    Description: 2016-07-23
    Keywords: Opal flux ; African margin ; African Humid Period ; Trade winds ; Abrupt change ; Deglaciation
    Repository Name: Woods Hole Open Access Server
    Type: Article
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