ALBERT

Description: We describe and analyze a statistical filtering approach for GRACE data that uses a parametrized model for the temporal evolution of the GRACE coefficients. After least-squares adjustment, a statistical test is performed to assess the significance of the estimated parameters. If the test is passed, the parameters are used by the filter in the reconstruction of the field; otherwise they are rejected. The test is performed, and the filter is formed, separately for annual components of the model and the trend. This new approach is distinct from Gaussian smoothing since it uses the data themselves to test for specific components of the time-varying gravity field. The statistical filter appears inherently to remove most of the "stripes" present in the GRACE fields, although destriping the fields prior to filtering seems to help the trend recovery. We demonstrate that the statistical filter produces reasonable maps for the annual components and trend. We furthermore assess the statistical filter for the annual components using ground-based GPS data in South America by assuming that the annual component of the gravity signal is associated only with groundwater storage. The un-destriped, statistically filtered field has a X2 value relative to the GPS data consistent with the best result from smoothing. In the space domain, the statistical filters are qualitatively similar to Gaussian smoothing. Unlike Gaussian smoothing, however, the statistical filter has significant sidelobes, including large negative sidelobes on the north-south axis, potentially revealing information on the errors, and the correlations among the errors, for the GRACE coefficients.

Description: Formation of self-assembled monolayer (SAM) of 4-aminothiophenol (4-ATP) on polycrystalline platinum electrodes has been studied by surface analysis and electrochemistry techniques. The 4-ATP monolayer was characterized by cyclic voltammetry (CV), Raman spectroscopy, reflection absorption infrared (RAIR) spectroscopy, and X-ray photoelectron spectroscopy (XPS). Cyclic voltammetry (CV) experiments give an idea about the packing quality of the monolayer. RAIR and Raman spectra for 4-ATP modified platinum electrodes showed the characteristic adsorption bands for neat 4-ATP indicating the adsorption of 4-ATP molecules on platinum surface. The adsorption on platinum was also evidenced by the presence of sulfur and nitrogen peaks by XPS survey spectra of the modified platinum electrodes. High resolution XPS studies and RAIR spectrum for platinum electrodes modified with 4-ATP indicate that molecules are sulfur-bonded to the platinum surface. The formation of S-Pt bond suggests that ATP adsorption gives up an amino terminated SAM. Thickness of the monolayer was evaluated via angle-resolved XPS (AR-XPS) analyses. Derivatization of 4-ATP SAM was performed using 16-Br hexadecanoic acid.