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  • Meteorology and Climatology  (1)
  • infrared solar observations  (1)
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  • 1
    ISSN: 1573-0662
    Keywords: HCN ; infrared solar observations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract A set of high-resolution IR solar spectra recorded at the International Scientific Station of the Jungfraujoch, Switzerland, from 84/06 to 93/06, and at the National Solar Observatory McMath-Pierce solar telescope facility on Kitt Peak, Arizona, U.S.A. from 78/05 to 92/07 have been analyzed to determine the vertical column abundances of hydrogen cyanide, HCN, above the two stations. The analysis was based on least-squares curve fitting of calculated spectra to the observations encompassing the P4 and the P8 lines of HCN respectively located at 3299.5273 and 3287.2483 cm−1. The results obtained for the two stations indicate that no significant long-term trend affects either of the two databases; however, this analysis reveals variable increases during springtime of up to a factor of 2 in the HCN total column above the Jungfraujoch and even up to 3 above Kitt Peak. The calculated mean vertical column abundances, excluding the spring observations, are equal to (2.55±0.30)×1015 molec./cm2 (S.D.) and (2.75±0.30)×1015 molec./cm2 respectively above the Jungfraujoch and the Kitt Peak observatories. Based on a realistic volume mixing ratio profile, these columns translate into mean volume mixing ratios equal to 190×10−12 ppv at the respective altitudes of the stations.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2019-07-18
    Description: A Sun photometer (18 channels between 300 and 1024 nm) has been used for measuring the columnar content of atmospheric water vapor (CWV) by solar transmittance measurements in absorption bands with channels centered at 719, 817, and 946 nm. The observable is the band-weighted transmittance function defined by the spectral absorption of water vapor and the spectral features of solar irradiance and system response. The transmittance function is approximated by a three-parameter model. Its parameters are determined from MODTRAN and LBLRTM simulations or empirical approaches using CWV data of a dual-channel microwave radiometer (MWR) or a Fourier transform spectrometer (FTS). Data acquired over a 2-year period during 1996-1998 at two different sites in Switzerland, Bern (560 m above sea level (asl)) and Jungfraujoch (3580 m asl) were compared to MWR, radiosonde (RS), and FTS retrievals. At the low-altitude station with an average CWV amount of 15 mm the LBLRTM approach (based on recently corrected line intensities) leads to negligible biases at 719 and 946 nm if compared to an average of MWR, RS, and GPS retrievals. However, at 817 nm an overestimate of 2.7 to 4.3 mm (18-29%) remains. At the high-altitude station with an average CWV amount of 1.4 mm the LBLRTM approaches overestimate the CWV by 1.0, 1.4. and 0.1 mm (58, 76, and 3%) at 719, 817, and 946 nm, compared to the ITS instrument. At the low-altitude station, CWV estimates, based on empirical approaches, agree with the MWR within 0.4 mm (2.5% of the mean); at the high-altitude site with a factor of 10 less water vapor the agreement of the sun photometers (SPM) with the ITS is 0.0 to 0.2 mm (1 to 9% of the mean CWV there). Sensitivity analyses show that for the conditions met at the two stations with CWV ranging from 0.2 to 30 mm, the retrieval errors are smallest if the 946 nm channel is used.
    Keywords: Meteorology and Climatology
    Type: Paper-2000JD900392 , Journal of Geophysical Research (ISSN 0148-0227); 105; D19; 24,327-24,343
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