ISSN:
0009-2940
Keywords:
Copper(II) complexes
;
Mangan(II) complexes
;
trinuclear
;
Schiff bases
;
macrocyclic
;
Redox properties
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Complexes with Macrocyclic Ligands, II. - Synthesis, Structure and Electrochemical Properties of a Macrocyclic Cu2IIMnII Complex of Schiff Base TypeA novel trinuclear Cu2Mn complex 4 of a macrocyclic Schiff base ligand obtained by condensation of 5-tert-butyl-2-hydroxy-1,3-benzenedicarbaldehyde with 1,2-phenylenediamine was synthesized. The molecular structure of 4 was determined by X-ray diffraction revealing a sandwich-type structure as depicted by Figure 2. Electrochemical investigations (DCV measurements) showed two one-electron reduction steps for the copper ions at E1/2 = -1.383 and -1.652 V (vs. Cp2Fe/Cp2Fe+).
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19941270605
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