ALBERT

Description: We have developed a new photochemical model of Titan's atmosphere which includes all the important compounds and reactions in spherical geometry from the surface to 1240 km. Compared to the previous model of Yung et al. (1984), the most significant recent change in the reactions used is the updated methane dissociation scheme (Mordaunt et al. 1993). Moreover, the transfer of the solar radiation in the atmosphere and the photolysis rates have been calculated by using a Monte Carlo code. Finally, the eddy diffusion coefficient profile is adjusted in order to fit the mean vertical distribution of HCN retrieved from millimeter groundbased observations of Tanguy et al. (1990); using new values for the boundary flux of atomic nitrogen (Strobel et al. 1992). We have run the model in both steady-state and diurnal modes, with 62 species involved in 249 reactions. There is little difference between diurnal and steady-state results. Overall our results are in a closer agreement with the abundances inferred from the Voyager infrared measurements at the equator than the Yung et al. results. We find that the catalytic scheme for H recombination invoked by Yung et al. only slightly improves the model results and we conclude that this scheme is not essential to fit observations.

Description: To investigate the occurrence of low temperatures and the formation of noctilucent clouds in the summer mesosphere, a one-dimensional time-dependent photochemical-thermal numerical model of the atmosphere between 50 and 120 km has been constructed. The model self-consistently solves the coupled photochemical and thermal equations as perturbation equations from a reference state assumed to be in equilibrium and is used to consider the effect of variability in water vapor in the lower mesosphere on the temperature in the region of noctilucent cloud formation. It is found that change in water vapor from an equilibrium value of 5 ppm at 50 km to a value of 10 ppm, a variation consistent with observations, can produce a roughly 15 K drop in temperature at 82 km. It is suggested that this process may produce weeks of cold temperatures and influence noctilucent cloud formation.

Description: We have investigated the transmission and albedo of the perennial ice cover on Lake Hoare, Antarctica. Our database consists of year-round measurements of the photosynthetically active radiation (400-700 nm) under the ice, measurements of the spatial variation of the under-ice light in midsummer, and spectrally resolved measurements from 400 to 700 nm of the albedo and transmission of the ice cover in early (November) and in midsummer (January). Our results show that the transmission decreases in the first part of summer, dropping by a factor of approximately 4 from November to January. We suggest that this is due to heating in the upper layers of the ice cover and the formation of Tyndall figures. Later in the summer when a significant liquid water fraction occurs within the ice cover, the transmission increases. In the fall when the ice cover freezes solid the transmission drops markedly. The spectrally resolved measurements from 400 to 700 nm show that approximately 2-5% of the incident light in this spectral region penetrates the 3.5-m thick ice cover. We have analyzed the spectral data using a two-stream scattering solution to the radiative transfer equation with three vertical layers in the ice cover. A surficial glaze of scattering ice 1 cm thick overlies a layer of sandy, bubbly ice about a meter thick, and below this is a thick layer of sand-free ice with bubbles. We find that the ice cover is virtually opaque at wavelengths longer than 800 nm. The net transmission of solar energy is approximately 2%. Significant changes in the thickness of the ice cover have been reported at Lake Hoare. These are due primarily to changes in the thickness of the bottom layer only. Because this layer is relatively clear, the effect on the transmission through the ice cover from these changes is less than would be predicted assuming a homogeneous ice cover.

Description: The application of radiocarbon dating is extended to include systems that are slowly exchanging carbon with the atmosphere. Simple formulae are derived that relate the true age and the exchange rate of carbon to the apparent radiocarbon age. A radiocarbon age determination does not give a unique true age and exchange rate but determines a locus of values bounded by a minimum age and a minimum exchange rate. It is found that for radiocarbon ages as large as 10,000 years it is necessary to correct for the anthropogenic radiocarbon produced in the atmosphere by nuclear weapons testing. A one-term exponential approximation, with an e-folding time of 14.43 years, is used to model this effect and is shown to be accurate to within 3 percent for exchange time constants of 100 years and greater. The approach developed here is not specific to radiocarbon and can be applied to other radioisotopes in open systems.