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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of industrial microbiology and biotechnology 11 (1993), S. 143-146 
    ISSN: 1476-5535
    Keywords: Citric acid production ; Candida guiliermondii ; Galactose ; Glucose ; Catabolite repression
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Summary A strain of the yeastCandida guilliermondii has been shown to produce citric acid from galactose to a similar extent, and at a similar rate, as from glucose. At an initial concentration of 36 g/l of either glucose or galactose, citric acid production exceeds 13 g/l. When galactose and glucose are present in a mixture, however, galactose utilization is delayed until most of the glucose has been utilized, providing evidence for catabolite repression.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 1 (1987), S. 319-323 
    ISSN: 0268-2605
    Keywords: Mössbauer ; Dibutyltin dichloride ; PVC ; Polymers ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Variable-temperature Sn-119m Mössbauer studies of tin(IV) chloride (SnCl4) and dibutyltin dichloride (Bu2SnCl2) when dispersed in a poly(vinyl chloride) (PVC) matrix have been interpreted using a Debye model. Recoilless fractions have been determined which indicate that at 80 K the Mössbauer technique is nearly three times as sensitive to the presence of SnCl4 compared with Bu2SnCl2 within the poly(vinyl chloride) matrix. These observations have been explained in terms of structural changes occurring on dispersion in the polymer matrix which result in the tin atom in tin(IV) chloride becoming six-coordinate whereas that in dibutyltin dichloride reduces its coordination to five. The implications of these results for future applications of Mössbauer spectroscopy to the study of organotin compounds present in polymers are considered.
    Additional Material: 2 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 3 (1989), S. 343-347 
    ISSN: 0268-2605
    Keywords: Triphenyltin ; neoprene ; elastomer ; Mössbauer ; degradation ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The fate of a series of triphenyltin biocides on incorporation into neoprene elastomers has been studied by 119mSn Mössbauer spectroscopy, together with supporting chemical derivatization techniques. It is shown that triphenyltin compounds undergo drastic degradation on incorporation into neoprene, suffering cleavage of phenyl-tin bonds to give a mixture of products in which all stages of dephenylation are present, including stannic chloride. This degradation occurs not only in elastomers cured at 150°C, but also in room temperature solvent-cast samples.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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