ISSN:
1042-7147
Keywords:
Metal alkyls
;
Purification
;
Poly(4-vinyl pyridine)
;
Adduct
;
Lewis base
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
Poly(4-vinyl pyridine) is used as a polymeric ligand to react with metal alkyls, MenM (n = 3, M = Al, Ga or In; n = 2, M = Cd or Zn) to form adducts. The adducts are characterized by solid state 13C NMR, infrared spectroscopy, microanalyses and differential scanning calorimetry (DSC). All the adducts are nonpyrophoric and thermally dissociable, so they may have potential both for use in adduct purification processes or for use as safer metal alkyl sources for Metal-Organic Chemical Vapor Deposition.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pat.1994.220050912
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