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  • LUNAR AND PLANETARY EXPLORATION  (854)
  • Physics  (339)
  • 1980-1984  (1,193)
  • 1960-1964
  • 1
    Electronic Resource
    Electronic Resource
    Aromatic polyamides. II. Thermal degradation of some aromatic polyamides and their model diamides (1981)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 19 (1981), S. 2817-2834 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Thermal degradation behavior of poly(1,3-phenylene isophthalamide) and poly(chloro-2,4-phenylene isophthalamide) was investigated with the aid of some appropriate model compounds. The pyrolysis products of these materials were identified by gas chromatography (GC), gas chromatography/Fourier transform infrared spectroscopy (GC/FT-IR), and gas chromatography/mass spectrometry (GC/MS). The residual chars were characterized by IR spectroscopy. Thermogravimetric analysis (TGA) was applied to study the effect of end-group concentration on the degradation characteristics of the two polyamides. Kinetic parameters that describe the thermal degradation of the polyamides were also evaluated by TGA. The results of this investigation suggest that the thermal decomposition of these aromatic polyamides involves homolytic as well as hydrolytic cleavages of the amide units.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1981.170191115
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Spectroscopic studies of solutions, suspensions, and precipitates of poly(1,6-di-p-toluene sulfonyloxy-2,4-hexadiyne) (1981)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 19 (1981), S. 321-334 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Optical-absorption, fluorescence, and Raman spectra for solutions, suspensions, and precipitates of poly(1,6-di-p-toluene sulfonoxy-2,4-hexadiyne) in and from nitrobenzene, acetone, and chloroform are presented. These are interpreted in terms of the occurrence of two forms of the polymer chain; a quasicrystalline form with properties close to those of single crystal polymer and a chain-extended form occurring in solution and colloidal particles, with an absorption energy of about 2.5 eV (20,000 cm-1). No evidence is found for the presence of very short polymer chains in partially polymerized monomer at low conversion. The relationship of these results to those for deformed single crystals is briefly discussed.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1981.180190212
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  • 3
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    Detection of the J-10 Manifold of the Pure Rotational Band of Phosphine on Saturn (1984)
    In:  CASI
    Details
    Publication Date: 2014-09-17
    Description: The detection of the J = 10 manifold of the pure rotational band of PH3 on Saturn is reported. The observations were made from the far-infrared cooled grating spectrometer. The wavelengths and observed brightness temperatures for the full disk plus rings are 89 + or - 3 K at 97.04 micrometer, 77 + or - 3 K at 102.72 micrometer, 77 + or - 3 K at 102.94 micrometer, and 83 + or - 3 K at 105.12 micrometers. The points of 97.04 and 105.12 micrometers establish the continuum level and the two points near 103 micrometers measure the depth of the PH3 manifold. After the flux due to the rings is subtracted, the depth of the feature is 16 + or - 6 K relative to the nearby 102 K continuum. These results are compared to theoretical models which parameterize the PH3 mixing ratio as x = x sub zero (P/P sub zero)(alpha) for P P sub zero and as x = x sub zero for P or = P, where P is the total pressure and alpha = H/h is the ratio of the dynamical scale height (H) and the scale height for decreasing the PH3 mixing ratio (h). The parameters x sub zero, P sub zero, and h were varied, as well as the H/He mixing ratio and the pressure-temperature profile. The data are well fitted using pressure-temperature profiles. The preferred values of h, P sub zero, and x sub zero imply that there is little or no PH3 above the thermal inversion and that the mixing ratio below the inversion is consistent with PH3 being 1 to 4 times overabundant relative to the solar P/H ratio.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Airborne Astron. Symp.; p 76-80
    Format: text
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  • 4
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    Preliminary results on the plasma environment of Saturn from the Pioneer 11 plasma analyzer experiment (1980)
    In:  Other Sources
    Details
    Publication Date: 2011-08-17
    Description: The Ames Research Center Pioneer 11 plasma analyzer experiment provided measurements of the solar wind interaction with Saturn and the character of the plasma environment within Saturn's magnetosphere. It is shown that Saturn has a detached bow shock wave and magnetopause quite similar to those at earth and Jupiter. The scale size of the interaction region for Saturn is roughly one-third that at Jupiter, but Saturn's magnetosphere is equally responsive to changes in the solar wind dynamic pressure. Saturn's outer magnetosphere is inflated, as evidenced by the observation of large fluxes of corotating plasma. It is postulated that Saturn's magnetosphere may undergo a large expansion when the solar wind pressure is greatly diminished by the presence of Jupiter's extended magnetospheric tail when the two planets are approximately aligned along the same solar radial vector.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Science; 207; Jan. 25
    Format: text
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  • 5
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    The chemistry of micrometeoroids (A0187-1) (1984)
    In:  CASI
    Details
    Publication Date: 2006-02-14
    Description: The prime objective of this experiment is to obtain chemical analyses of a statistically significant number of micrometeoroids. These data will then be compared with the chemical composition of meteorites. Secondary objectives of the experiment relate to density, shape, mass frequency, and absolute flux of micrometeorids as deduced from detailed crater geometrics (depth) diameter, and plane shape, and number of total events observed.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: NASA. Langley Research Center Long Duration Exposure Facility (LDEF); p 127-130
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  • 6
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    Discovery of natural gain amplification in the 10-micrometer carbon dioxide laser bands on Mars - A natural laser (1981)
    In:  Other Sources
    Details
    Publication Date: 2011-08-18
    Description: Fully resolved intensity profiles of various lines in the carbon dioxide band at 10.4 micrometers have been measured on Mars with an infrared heterodyne spectrometer. Analysis of the line shapes shows that the Mars atmosphere exhibits positive gain in these lines. The detection of natural optical gain amplification enables identification of these lines as a definite natural laser.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Science; 212; Apr. 3
    Format: text
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  • 7
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    The atmosphere of Jupiter - An analysis of the Voyager radio occultation measurements (1981)
    In:  Other Sources
    Details
    Publication Date: 2011-08-18
    Description: Coherently related S and X band signals of 2.3 and 8.4 GHz, respectively, which were transmitted from Voyagers 1 and 2 were used to probe the Jovian atmosphere. Height profiles of the gas refractivity, molecular number density, pressure, temperature, and microwave absorption in the troposphere and stratosphere were observed at latitudes ranging from 0 to 70 deg S. At 1000 mbar, the temperature was + or - 5 K and the lapse rate was equal to the adiabatic value of 2.1 K/km within the resolution of the measurements. The ammonia abundance in this region was 0.022 + or - 0.008%, which is in good agreement with values derived from cosmic abundance considerations. The tropopause at the 140 mbar level had a temperature of 110 K, which increased with increasing altitude, reaching 160 + or - 20 K in the 10 to 1 mbar region. Significant horizontal density variations were detected in the stratosphere, which implies a nonuniform temperature and aerosol distribution across the Jovian disk or across high- and low-pressure regions due to local atmospheric dynamics.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Journal of Geophysical Research; 86; Sept. 30
    Format: text
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  • 8
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    Observations of the 10-micron natural laser emission from the mesospheres of Mars and Venus (1983)
    In:  Other Sources
    Details
    Publication Date: 2011-08-18
    Description: Observations of the total flux and center to limb dependence of the nonthermal emission occurring in the cores of the 9.4 and 10.4 micrometers CO2 bands on Mars are compared to a theoretical model based on this mechanism. The model successfully reproduces the observed center to limb dependence of this emission, to within the limits imposed by the spatial resolution of the observations of Mars and Venus. The observed flux from Mars agrees closely with the prediction of the model; the flux observed from Venus is 74 percent of the flux predicted by the model. This emission is used to obtain the kinetic temperatures of the Martian and Venusian mesospheres. For Mars near 70 km altitude, a rotational temperature analysis using five lines gives T = 135 + or - 20 K. The frequency width of the emission is also analyzed to derive a temperature of 126 + or - 6 K. In the case of the Venusian mesosphere near 109 km, the frequency width of the emission gives T = 204 + or - 10 K.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Icarus (ISSN 0019-1035); 55; Sept
    Format: text
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  • 9
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    Far-infrared spectrophotometry of Saturn and its rings (1982)
    In:  Other Sources
    Details
    Publication Date: 2011-08-18
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Icarus; 51; Sept
    Format: text
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  • 10
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    Measurements of stratospheric ethane in the Jovian South Polar Region from infrared heterodyne spectroscopy of the nu9 band near 12 microns (1983)
    In:  Other Sources
    Details
    Publication Date: 2011-08-18
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Astrophysical Journal; vol. 265
    Format: text
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