ALBERT

Description: The 7.8 micrometer emission from the nu(sub 4) band of methane (CH4) is a regularly observed feature in the stratosphere of all the giant planets and Titan. On Jupiter, enhancements in this emission are associated with the infrared hot spots in the auroral zone. Attempts to model this phenomenon in particular, and to understand the role of methane in general, have been hampered in part by a lack of adequate laboratory measurements of the collisional relaxation times for the nu(sub 3) and nu(sub 4) levels over the appropriate temperature range. To provide this needed data, a series of laboratory experiments were initiated. In the experimental arrangement the nu(sub3) band of methane is pumped at 3.3 micrometers using a pulsed infrared source (Nd:YAG/dye laser system equipped with a wave-length extender). The radiative lifetime of the nu(sub 3) level (approximately 37 ms) is much shorter than the nu(sub 4) lifetime (approximately 390 ms); however, a rapid V-V energy transfer rate ensures that the nu(sub 4) level is substantially populated. The photoacoustic technique is used to acquire relaxation rate information. The experiments are performed using a low-temperature, low-pressure cell. Experimental apparatus and technique are described. In addition some of the experimental difficulties associated with making these measurements are discussed and some preliminary results are presented.

Description: The rocks and soils of the Moon will be the raw materials for fuels and construction needs at a lunar base. This includes sources of materials for the generation of hydrogen, oxygen, metals, and other potential construction materials. For most of the bulk material needs, the regolith, and its less than 1 cm fraction, the soil, will suffice. But for specific mineral resources, it may be necessary to concentrate minerals from rocks or soils, and it is not always obvious which is the more appropriate feedstock. Besides an appreciation of site geology, the mineralogy and petrography of local rocks and soils is important for consideration of the resources which can provide feedstocks of ilmenite, glass, agglutinates, anorthite, etc. In such studies, it is very time-consuming and practically impossible to correlate particle counts (the traditional method of characterizing lunar soil petrography) with accurate modal analyses and with mineral associations in multi-mineralic grains. But x ray digital imaging, using x rays characteristic of each element, makes all this possible and much more (e.g., size and shape analysis). An application of beneficiation image analysis, in use in our lab (Oxford Instr. EDS and Cameca SX-50 EMP), was demonstrated to study mineral liberation from lunar rocks and soils. Results of x ray image analysis are presented.

Description: The pristine glasses of Delano are the most primitive lunar basaltic magma compositions discovered to date. They are grouped into two (and possibly three) arrays: a low-alumina array and a high alumina array. These glasses are very olivine normative and are multiply saturated at pressures of approximately 20 kbar, implying a depth of origin of 400 to 500 km in the Moon. Thus, these glasses appear to be the best candidates for primitive partial melts of the upper lunar mantle. One of the most perplexing characteristics of the pristine glasses is a positive correlation between Ni and SiO2 within each array. This is contrary to the terrestrial experience, where Ni is observed to positively correlate with MgO and negatively correlate with SiO2. These systematics are believed to be due to the depletion of Ni by olivine fractionation. The difference between the lunar and terrestrial Ni vs. SiO2 trends may be partially ascribed to the Ti-rich component. In the case of the pristine glasses, SiO2 increases not because of olivine fractionation, but because they contain less of the high-Ti component. An attempt was made to model this variation in Ni and SiO2 with a simple assimilation-fractional crystallization (AFC) model. Silica and Ni both decreased dramatically as the AFC process proceeded. Only 15 to 20 percent AFC was necessary to produce the observed variation, and the SiO2 vs. Ni variation was modeled quite well. The D(Ni) for olivine/liquid in this model was taken to be 10 and the olivine was assumed to be Fe sub 80. However, the results of this model for Ti and Mg were less than satisfactory. It seemed difficult to achieve the high TiO2 contents of some glasses (16 to 17 wt. percent) by this method. Continual addition of ilmenite by AFC could indeed raise the titania concentrations to the necessary levels, but only by enriching the magma in FeO and greatly depleting the magma in MgO. An attempt was made to circumvent this problem by using armalcolite, (Fe, Mg)Ti2O5, in the AFC model, and the results are presented.

Description: The pneumatic soil sampler concept was successfully demonstrated by penetrating a Martian simulant soil to a depth of 2 meters. Working gas pressure, composition, and pulsing were evaluated with the objective of minimizing gas usage. Also, the probe penetration force was investigated with the objective of minimizing probe weight. Gas and probe penetration force, while not yet optimized, are within the range which make the soil sampler concept feasible. While the tests described in this report did not answer all the questions and address all the variables associated with pneumatic soil sampling, valuable data experience and knowledge were gained which can be used to further develop the concept.

Description: Research effort included the PLS data analysis program where modifications to the data fitting procedure and elimination of possible noise and electron contamination were made. The analysis code corrections were used in checking the Neptune data gathered during the Voyager 2 encounter and for analyzing selected plasma spectra from the warm Io torus. A major task accomplished was the summary of Uranus-related research in the U.S. National Report to the International Union of Geodesy and Geophysics for the 1987 - 1990 quadrennium. A limited amount of work was accomplished on assessing the Pedersen conductivity of the ionosphere and comparing it with inferred values from shielding by the Uranian ring current. Under this grant there has been a great deal of effort expended on identifying and classifying plasma waves and oscillations in the magnetosheath and solar wind downstream from Uranus. Large amplitude oscillations in plasma parameters are found in the magnetosheath, with density changes of up to a factor of ten occurring on times scales of minutes. New algorithms developed for analyzing the inbound bow shock crossing of Neptune will probably be applied to a more detailed analysis of the Uranus shock in the near future.

Description: This paper gives a complete overview of the plasma and magnetic field in the magnetosheath of Neptune. A more sophisticated method is used to reanalyze the plasma data. This method provides better values of plasma density, velocity, and temperature in the magnetosheath both inbound and outbound from the planet than published previously. The data are compared to results obtained from a gasdynamic model of low around a planetary magnetosphere. Agreement of theory and data is good for some parameters and poor for others. We show that some discrepancies between the model predictions and observations may be due to changes in the solar wind parameters. The model results and data are used to check the hypothesis that Voyager encountered the high-latitude plasma mantle downstream from Neptune. The deviations of the data from the model results in this region are consistent with those expected for a mantle crossing, with the exception of the plasma temperature which decreases in one crossing and increases in the other. This may indicate that our knowledge of the nature of the mantle-magnetosheath boundary is not complete.

Description: The Langley cosmic ray transport code and the Langley nucleon transport code are used to quantify the transport and attenuation of galactic cosmic rays and solar proton flares through the Martian atmosphere. Surface doses are estimated using both a low-density and a high-density carbon dioxide model of the atmosphere which, in the vertical direction, provide a total of 16 g/sq cm and 22 g/sq cm of protection, respectively. At the Mars surface during the solar minimum cycle, a blood-forming organ (BFO) dose-equivalent of 10.5 to 12 rem/yr due to galactic cosmic ray transport and attenuation is calculated. Estimates of the BFO dose-equivalents which would have been incurred at the surface from three large solar flare events are also calculated. Doses are also estimated at altitudes up to 12 km above the Martian surface where the atmosphere will provide less total protection.

Description: The Voyager plasma experiment observed large-amplitude plasma fluctuations in the Uranian magnetosheat downstream from the planet. This is a region that has not been well sampled in the earth's magnetosphere. These waves have periods of tens of minutes, are characterized by an anticorrelation between the plasma density and temperature, and are associated with deflections in the flow angle of the plasma. These fluctuations are observed only in regions where the magnetic field is rapidly varying. These waves have time and distance scales placing them in the MHD regime, but their characteristics are not compatible with any known solution of the MHD equations. It is suggested that these fluctuations are produced by the solar wind interaction with the magnetosphere at the bow shock, but the physics governing the production and propagation of these fluctuations is not understood.

Description: A bulk composition for Mars is derived to a pressure-dependent mineralogy. The density distribution of the present model is compared with density distributions derived from the global gravity field. It is argued that the uppermost Martian mantle is likely to be dominated by olivine and orthopyroxene, as is the earth's upper mantle, although the Martian mantle has a lower MgO/(MgO + FeO) ratio (0.74 vs 0.89). The olivine-peridotite layer extends to a depth of 900 to 1100 km where the transition to silicate spinel begins. Calculations of the high-pressure liquidus and solidus temperatures indicate that for the case of a molten core the minimum temperature at the core-mantle boundary is about 2000 K, whereas for the case of a solid core the maximum temperature is about 1800 K. Summation of the masses in the various layers of Mars yields a value of 0.353 for the dimensionless moment of inertia, which is intermediate between the generally accepted value of 0.365 and the value of 0.345 predicated on a nonaxisymmetric distribution of mass about the Tharsis plateau.

Description: Polar projections of 50 images of Saturn at 889 nanometers and 25 images at 718 nanometers taken by the HST in November 1990, as well as three images at each wavelength taken in June 1991, have been examined. Among them, 31 show the north polar spot, which is associated with Saturn's polar hexagon, in locations suitable for measurement. The movement of the spot with respect to Saturn's system III rotation rate was studied. During the period of observation, the polar spot had first a short-term westward movement and then a long-term eastward drift. The rate of the long-term drift was -0.060 +/- 0.008 deg/day with respect to system III, approximately 50 percent greater than previously determined from Voyager. The original 1980 and 1981 Voyager data were combined with the new Hubble images to form an 11-yr baseline. The eastward drift over the longer period was -0.0569 degrees per day. The long-term drift could be due to uncertainty in the standard value of the internal rotation period. The short-term movement in November 1990 has a rate that is greater in magnitude but opposite in sign and probably represents a real, transient motion of the spot relative to the internal rotation system.