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  • 97.10  (1)
  • Key wordsSpectroelectrochemistry  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solid state electrochemistry 1 (1997), S. 62-67 
    ISSN: 1433-0768
    Keywords: Key wordsSpectroelectrochemistry ; Diffuse reflectance spectrometry ; Solid state electrochemistry ; Voltammetry ; Microscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract An instrumental setup is described which allows electrochemical measurements to be performed with solid particles immobilized on the surface of a graphite electrode with in situ recording of diffuse reflectance spectra under an incident light microscope. The instrument used includes a special electrochemical cell and a microscope which is interfaced by a light␣guide to a transputer-integrated photodiode-array spectrometer allowing measurements ranging from 320 to 950 nm with a resolution of 3.2 nm/pixel and a PC-interfaced potentiostat. The 0R0 geometry of the optical arrangement and the use of crossed polarization filters for blocking specular reflectance makes it possible to use the Kubelka-Munk function for quantifying the optical measurements. The above instrument has been used for the study of the electrochromic system of solid silver octacyanomolybdate(IV/V) adjacent to a silver nitrate solution. The in situ diffuse reflec tance spectroelectrochemical measurements prove that the electrochemical reaction starts at the graphite/sample interface and then advances into the bulk of the sample towards the sample/electrolyte interface. The ratios Red:Ox determined by spectrometry and chronocoulometry as a function of electrode potentials are identical.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 334 (1989), S. 491-510 
    ISSN: 1434-601X
    Keywords: 25.55 ; 97.10
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The22Ne(α, γ)26Mg and22Ne(α, n)25Mg reactions were investigated forE α(lab) from 0.71 to 2.25 MeV. Neon gas enriched to 99% in22Ne was recirculated in a differentially pumped gas target system of the extended type. Theγ-ray transitions were observed with Ge(Li) detectors and the neutrons with3He ionization chambers. A previously known resonance at ER(lab)=2.05 MeV was verified and 15 new resonances were found in the energy range covered, with the lowest at ER(lab)=0.83 MeV. Information on resonance energies, widths, strengths,γ-ray branching ratios, as well asJ π assignments, is reported. The energy range investigated corresponds to the important temperature range ofT 9 from 0.3 to 1.4 (109 K), for which the astrophysical rates were determined for both reactions. The results show that the ratios of the rates for22Ne(α, n)25Mg and22Ne(α, γ)26Mg are significantly smaller than the previously adopted values, e.g., by at least a factor of 60 nearT 9=0.65. Thus, the22Ne(α, n)25Mg reaction will likely play a smaller role as a neutron source fors-process nucleosynthesis, than has frequently been assumed.
    Type of Medium: Electronic Resource
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