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  • General Chemistry  (2)
  • Epoxidations  (1)
  • Key words: Tree-growing algorithm, segmentation tree, decision tree, information content measure, symbolic data analysis  (1)
  • 2000-2004  (3)
Collection
Keywords
Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Computational statistics 15 (2000), S. 13-24 
    ISSN: 1613-9658
    Keywords: Key words: Tree-growing algorithm, segmentation tree, decision tree, information content measure, symbolic data analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Summary Based in a generalised recursive tree-building algorithm for populations partitioned into strata a method to obtain simple descriptions of strata is presented. Also strata with a common rule are obtained. Common predictors and criterion variable describe population in all strata or classes of individuals. Algorithm considers strata structure in tree-building algorithm and combines in each step maximisation of an information content measure for the criterion variable in a new binary partition of the population and selection of decisional nodes, based in quality of prediction for subsets of strata. Each decisional tree node is composed of a set of strata and a rule for individuals in these strata that will jointly explain the criterion variable. Symbolic data analysis fits the method. Input of the algorithm is composed of classes of individuals. Algorithm is extended to individuals described by probabilistic symbolic objects. As output, symbolic objects describe tree, decisional nodes and strata.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1434-1948
    Keywords: Silicon ; Silyl anions ; Lithium ; Silanes ; Polysilyl dianions ; α,ω-Dilithiooligosilanes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: (Me3Si)3Si(Me2Si)2(Me3Si)2SiLi (1) and LiSi(Me3Si)2(Me2Si)2Si(Me3Si)2Li (2) were synthesized by the reaction of (Me3Si)3Si(Me2Si)2Si(Me3Si)3 in THF with one or two mol-equivalents, respectively, of MeLi. Both 1 and 2 were characterized spectroscopically and by trapping reactions, and 1 also by X-ray crystallography.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 2000 (2000), S. 1387-1389 
    ISSN: 1434-193X
    Keywords: Natural products ; Epoxidations ; Asymmetric synthesis ; Fluorine ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---The synthesis of enantiomerically and diastereomerically pure (-)-(1R,2R,5R)- and (-)-(1R,2S,5R)-2-fluoro frontalin (7) starting from (+)-(1S)-menthyl-(R)-toluene-4-sulfinate, methylmagnesium bromide, methyl fluoroacetate, 4-pentenyl bromide and diazomethane is described. The absolute stereochemistry was unambiguously determined by X-ray analysis of (+)-(1S,2R,5S,RS)-5, an intermediate in the synthesis of the enantiomeric (+)-(1S,2R,5S)-2-fluoro frontalin (7).
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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