ISSN:
1434-193X
Keywords:
Photochemistry
;
Matrix isolation
;
Density functional calculations
;
Isomerizations
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
---Ultraviolet irradiation of matrix-isolated formamide (1) in solid argon with light of wavelength 248 nm leads to the formation of formimidic acid (2). Comparison of the experimental IR spectrum of the photoproduct with the calculated IR spectrum of 2 shows clearly that two rotamers 2a and 2b are formed.Supporting information for this article is available on the WWW under //http://www.wiley-vch.de/contents/jc_2046/2000/99501_s.pdf or from the author.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
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