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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 13 (1984), S. 647-661 
    ISSN: 1572-8927
    Keywords: Ionization ; carbonic acid ; equilibrium ; high temperature ; thermodynamics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The equilibrium quotients for the first ionization of aqueous carbon dioxide were previously determined at this laboratory. A similar potentiometric technique has now been employed to determine the second ionization quotients in NaCl media to 5m and from 50 to 250°C. The results have been combined with selected information in the literature and modeled to derive thermodynamic parameters including equilibrium constants, activity coefficient quotients, changes in enthalpies and changes in heat capacity along the saturation pressure curve. Approximate values for pressure coefficients were obtained to permit the short extrapolations from experimental conditions to the saturation pressure condition. The results demonstrate that log K2/Kw, when plotted vs. 1/T, gives nearly a straight line as has been observed for a number of other such processes. This provides the best means of extrapolation beyond the temperature of the measurements. The results have been applied to an examination of the solubility of calcite (calcium carbonate) as a function of hydrogen ion molality (in a given NaCl medium) for the condition where the calcium ion molality equals the total carbonate molality (in all forms).
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 2 (1982), S. 239-251 
    ISSN: 0271-2091
    Keywords: Regular ; Discontinuous Boundary Elements ; Fluid Flow ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The Boundary Element Method is now well established as a valid numerical technique for the solution of field problems, equal to the Finite Element Method in generality and surpassing it in computational efficiency in some cases.1 In this paper is presented a 'Regular Boundary Element Method' as applied to inviscid laminar fluid flow problems. It involves the formation of a system of regular integral equations obtained by moving the singularity outside the domain of the given problem. It is also shown that non-conforming elements may be used whereby freedoms are not defined at the geometric nodes under the boundary element discretization. A linear element is developed here; higher order variants could easily be defined. Satisfactory numerical results have been obtained using the proposed regular method with both conventional (continuous across the boundary) and non-conforming boundary elements for two-dimensional inviscid laminar fluid flow problems having regular and singular solutions.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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