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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 31 (2016): 472–490, doi:10.1002/2015PA002917.
    Description: Compilations of paleoceanographic observations for the deep sea now contain a few hundred points along the oceanic margins, mid-ocean ridges, and bathymetric highs, where seawater conditions are indirectly recorded in the chemistry of buried benthic foraminiferal shells. Here we design an idealized experiment to test our predictive ability to reconstruct modern-day seawater properties by considering paleoceanographic-like data. We attempt to reconstruct the known, modern-day global distributions by using a state estimation method that combines a kinematic tracer transport model with observations that have paleoceanographic characteristics. When a modern-like suite of observations (Θ, practical salinity, seawater δ18O, inline image, PO4, NO3, and O2) is used from the sparse paleolocations, the state estimate is consistent with the withheld data at all depths below 1500 m, suggesting that the observational sparsity can be overcome. Physical features, such as the interbasin gradients in deep inline image and the vertical structure of Atlantic inline image, are accurately reconstructed. The state estimation method extracts useful information from the pointwise observations to infer distributions at the largest oceanic scales (at least 10,000 km horizontally and 1500 m vertically) and outperforms a standard optimal interpolation technique even though neither dynamical constraints nor constraints from surface boundary fluxes are used. When the sparse observations are more realistically restricted to the paleoceanographic proxy observations of δ13C, δ18O, and Cd/Ca, however, the large-scale property distributions are no longer recovered coherently. At least three more water mass tracers are likely needed at the core sites in order to accurately reconstruct the large-scale property distributions of the Last Glacial Maximum.
    Description: NSF Grant Numbers: 1124880, 1125422
    Description: 2016-10-08
    Keywords: Water mass geometry ; Tracer distributions ; Inverse methods ; Last Glacial Maximum ; Identical twin experiment ; Isotope records
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 2
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 27 (2012): PA3225, doi:10.1029/2011PA002273.
    Description: The midpoint of the Last Termination occurred 4,000 years earlier in the deep Atlantic than the deep Pacific according to a pair of benthic foraminiferal δ18O records, seemingly implying an internal circulation shift because the lag is much longer than the deep radiocarbon age. Here a scenario where the lag is instead caused by regional surface boundary condition changes, delays due to oceanic transit timescales, and the interplay between temperature and seawater δ18O (δ18Ow) is quantified with a tracer transport model of the modern-day ocean circulation. Using an inverse method with individual Green functions for 2,806 surface sources, a time history of surface temperature and δ18Ow is reconstructed for the last 30,000 years that is consistent with the foraminiferal oxygen-isotope data, Mg/Ca-derived deep temperature, and glacial pore water records. Thus, in the case that the ocean circulation was relatively unchanged between glacial and modern times, the interbasin lag could be explained by the relatively late local glacial maximum around Antarctica where surface δ18Ow continues to rise even after the North Atlantic δ18Ow falls. The arrival of the signal of the Termination is delayed at the Pacific core site due to the destructive interference of the still-rising Antarctic signal and the falling North Atlantic signal. This scenario is only possible because the ocean is not a single conveyor belt where all waters at the Pacific core site previously passed the Atlantic core site, but instead the Pacific core site is bathed more prominently by waters with a direct Antarctic source.
    Description: G.G. is supported by NSF grant OIA-1124880 and the WHOI Arctic Research Initiative.
    Description: 2013-03-06
    Keywords: Deglaciation ; Foraminiferal data ; Inverse methods ; Numerical modeling ; Oxygen-18 ; Tracers
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 3
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2015. This is the author's version of the work. It is posted here by permission of Elsevier for personal use, not for redistribution. The definitive version was published in Quaternary Science Reviews 125 (2015): 144-159, doi:10.1016/j.quascirev.2015.08.010.
    Description: A paleo-data compilation with 492 δ13C and δ18O observations provides the opportunity to better sample the Last Glacial Maximum (LGM) and infer its global properties, such as the mean δ13C of dissolved inorganic carbon. Here, the paleocompilation is used to reconstruct a steady-state water-mass distribution for the LGM, that in turn is used to map the data onto a 3D global grid. A global-mean marine δ13C value and a self-consistent uncertainty estimate are derived using the framework of state estimation (i.e., combining a numerical model and observations). The LGM global-mean δ13C is estimated to be 0:14h±0:20h at the two standard error level, giving a glacial-to-modern change of 0:32h±0:20h. The magnitude of the error bar is attributed to the uncertain glacial ocean circulation and the lack of observational constraints in the Pacific, Indian, and Southern Oceans. Observations in the Indian and Pacific Oceans generally have 10 times the weight of an Atlantic point in the computation of the global mean. To halve the error bar, roughly four times more observations are needed, although strategic sampling may reduce this number. If dynamical constraints can be used to better characterize the LGM circulation, the error bar can also be reduced to 0:05 to 0:1h, emphasizing that knowledge of the circulation is vital to accurately map δ13CDIC in three dimensions.
    Description: GG is supported by NSF grants OIA-1124880 and OCE-1357121, the WHOI Ocean and Climate Change Institute, and The Joint Initiative Awards Fund from the Andrew W. Mellon Foundation.
    Keywords: Paleoceanography ; Physical Oceanography ; Carbon reservoirs ; Last Glacial Maximum ; Inverse methods
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
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  • 4
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    American Geophysical Union
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 38 (2011): L06604, doi:10.1029/2011GL046769.
    Description: The ocean surface rapidly exchanges heat, freshwater, and gases with the atmosphere, but once water sinks into the ocean interior, the inherited properties of seawater are closely conserved. Previous water-mass decompositions have described the oceanic interior as being filled by just a few different property combinations, or water masses. Here we apply a new inversion technique to climatological tracer distributions to find the pathways by which the ocean is filled from over 10,000 surface regions, based on the discretization of the ocean surface at 2° by 2° resolution. The volume of water originating from each surface location is quantified in a global framework, and can be summarized by the estimate that 15% of the surface area fills 85% of the ocean interior volume. Ranked from largest to smallest, the volume contributions scaled by surface area follow a power-law distribution with an exponent of −1.09 ± 0.03 that appears indicative of the advective-diffusive filling characteristics of the ocean circulation, as demonstrated using a simple model. This work quantifies the connection between the surface and interior ocean, allowing insight into ocean composition, atmosphere-ocean interaction, and the transient response of the ocean to a changing climate.
    Description: GG and PH were funded by NSF award 0645936. GG was also supported by the J. Lamar Worzel Assistant Scientist Fund and the Penzance Endowed Fund in Support of Assistant Scientists. PH was also supported by NSF award OCE‐0960787.
    Keywords: Water masses ; Deep-water formation ; Physical oceanography ; Ocean pathways ; Inverse methods ; Steady-state circulation
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 5
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    John Wiley & Sons
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2014. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 29 (2014): 190-209, doi:10.1002/2013PA002557.
    Description: Observations of δ13C and Cd/Ca from benthic foraminifera have been interpreted to reflect a shoaling of northern source waters by about 1000 m during the Last Glacial Maximum, with the degree of shoaling being significant enough for the water mass to be renamed Glacial North Atlantic Intermediate Water. These nutrient tracers, however, may not solely reflect changes in water mass distributions. To quantify the distribution of Glacial North Atlantic Water, we perform a glacial water mass decomposition where the sparsity of data, geometrical constraints, and nonconservative tracer effects are taken into account, and the extrapolation for the unknown water mass end-members is guided by the modern-day circulation. Under the assumption that the glacial sources of remineralized material are similar to that of the modern day, we find a steady solution consistent with 241 δ13C, 87 Cd/Ca, and 174 δ18O observations and their respective uncertainties. The water mass decomposition indicates that the core of Glacial North Atlantic Water shoals and southern source water extends in greater quantities into the abyssal North Atlantic, as previously inferred. The depth of the deep northern-southern water mass interface and the volume of North Atlantic Water, however, are not grossly different from that of the modern day. Under this scenario, the vertical structure of glacial δ13C and Cd/Ca is primarily due to the greater accumulation of nutrients in lower North Atlantic Water, which may be a signal of the hoarding of excess carbon from the atmosphere by the glacial Atlantic.
    Description: G.G. is supported by NSF grants OIA-1124880 and OCE-1301907, and the WHOI Ocean and Climate Change Institute.
    Description: 2014-09-13
    Keywords: Water mass geometry ; Tracer distributions ; Inverse methods ; Remineralization ; Last Glacial Maximum ; Circulation variability
    Repository Name: Woods Hole Open Access Server
    Type: Article
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