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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 23 (1985), S. 3031-3044 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Four novel semirigid poly(amide-ester)s having the same ordered amide-amide-ester-ester (-AAEE-) and the same or the different phenyl structure were synthesized from the various combination of active acylamide of benzotriazole (HBT) such as 1,1′-(isophthaloyl)bisbenzotriazole (IPBBT) and 1,1′-(terephthaloyl)bisbenzotriazole (PBBT) with diols such as N,N'-bis(2-hydroxyethyl)isophthamide (HEIPA) and N,N'-bis(2-hydroxyethyl)terephthamide (HEPTA) which prepared from the selective N-acylation of IPBBT or PBBT with aminoethanol in excellent yield at room temperature. Before the preparation of diol monomers, a model reaction of selective N-acylation was also completed from active monoacylamide of benzotriazole, 1-benzoylbenzotriazole with aminoethanol. The ordered structure of poly(amideester)s were characterized by infrared (IR) and NMR spectra. On the bases of different reactivity between selective N-acylation and O-acylation of active acylamide of benzotriazole, poly(amide-ester)s having the ordered AAEE and the same phenyl structure were also readily synthesized from the IPBBT or PBBT with aminoethanol under mild conditions by one-bath process.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 525-536 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Preparations of four diol monomers containing nucleic acid bases and the corresponding model polymers of polynucleotides with linear polyester backbone and nucleic acid base derivative as pending side chains are described. N-(1′,3′-Dihydroxy-2′-methyl-2′-propyl)-2-(thymin-l-yl)propionamide (Ia, HMPTPA), N-(1′,3′-dihydroxy-2-methyl-2′-propyl)-2-(uracil-l-yl)propionamide (Ib, HMPUPA), and their isomers, N-(β,β′-dihydroxyethyl)-2-(thynin-1-yl)propionamide (IIa, HETPA) and N-(β,β′-dihydroxyethyl)-2-(uracil-1-yl)propionamide (IIb, HEUPA) were synthesized through the selective N-acylation of 2-methyl-2-amino-1,3-propanediol and diethanolamine with 2-(thymin-1-yl)propionic acid (TPA) and 2-(uracil-1-yl)propionic acid (UPA), respectively, by the active amide-benzotriazole method. Diol monomers I and II were polycondenzed with active amide of benzotriazole such as 1,1′-(isophthaloyl)bisbenzotriazole (IPBBT) in the presence of triethylamine and in DMF at 60°C, giving polyesters containing thymine and uracil derivatives as the side group. Prior to polymer synthesis, an O-acylation of Ia using the active monoamide l-benzoylbenzotriazole was carried out as a model compound study.
    Additional Material: 2 Ill.
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  • 3
    ISSN: 1022-1344
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The purpose of this paper is to construct a unified theoretical framework to link micro to macro-mechanical properties of glassy polymers. Starting from a model of microcrack propagation in craze on a mesoscale, the kinetic process of microcrack propagation resulting from fibril breakdown in the crack tip zone is mathematically formulated by a combination of fracture mechanics and fracture kinetics. A microcrack evolution equation involving both the geometric structure parameters of craze and the meso-mechanical quantities is obtained. After solving this evolution equation, a statistical distribution function of microcrack size which evolves with time and the moment generating function of microcrack size are derived. Any-order averaged damage functions can be therefore deduced. Specifically, the analytical expressions of the first-order averaged damage function and its damage rate are presented, which correspond to a similar definition of damage mechanics.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Publication Date: 2022-05-26
    Description: Author Posting. © American Meteorological Society, 2009. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Atmospheric and Oceanic Technology 26 (2009): 2228-2242, doi:10.1175/2009JTECHO652.1.
    Description: The performance of pressure sensor–equipped inverted echo sounders for monitoring nonlinear internal waves is examined. The inverted echo sounder measures the round-trip acoustic travel time from the sea floor to the sea surface and thus acquires vertically integrated information on the thermal structure, from which the first baroclinic mode of thermocline motion may be inferred. This application of the technology differs from previous uses in that the wave period (30 min) is short, requiring a more rapid transmission rate and a different approach to the analysis. Sources of error affecting instrument performance include tidal effects, barotropic adjustment to internal waves, ambient acoustic noise, and sea surface roughness. The latter two effects are explored with a simulation that includes surface wave reconstruction, acoustic scattering based on the Kirchhoff approximation, wind-generated noise, sound propagation, and the instrument’s signal processing circuitry. Bias is introduced as a function of wind speed, but the simulation provides a basis for bias correction. The assumption that the waves do not significantly affect the mean stratification allows for a focus on the dynamic response. Model calculations are compared with observations in the South China Sea by using nearby temperature measurements to provide a test of instrument performance. After applying corrections for ambient noise and surface roughness effects, the inverted echo sounder exhibits an RMS variability of approximately 4 m in the estimated depth of the eigenfunction maximum in the wind speed range 0 ≤ U10 ≤ 10 m s−1. This uncertainty may be compared with isopycnal excursions for nonlinear internal waves of 100 m, showing that the observational approach is effective for measurements of nonlinear internal waves in this environment.
    Description: This project was supported by the ONR Nonlinear Wave Program under Contract N0014-05-1-0286.
    Keywords: Acoustic measurements/effects ; Internal waves ; Instrumentation/sensors ; Temperature
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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