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  • 1
    Electronic Resource
    Electronic Resource
    Zur Kenntnis der Verbindungen MIISnF6 mit MII = Mn, Fe, Zn, Hg, Pb) bzw. Co, Ni, Cu, Cd) (1972)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 392 (1972), S. 1-9 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the compounds MIISnF6 with MII = Mn, Fe, Zn, Hg, Pb or Co, Ni, Cu, Cd.Hitherto unknown MnSnF6 (a = 5.416, c = 14.136 Å), FeSnF6 (a = 5.270, c = 14.063 Å), ZnSnF6 (a = 5.216, c = 13.801 Å), CoSnF6 (a = 5.211, c = 13.933 Å), NiSnF6 (a = 5.152, c = 13.763 Å), CuSnF6 (a = 5.13, c = 13.82 Å), all hex. isotypic with LiSbF6; HgSnF6 (a = 5.321, c = 15.027 Å) hex. isotypic with VF3; and CdSnF6 (a = 5.37, c = 14.47 Å) hex. isotypic with VF3 or LiSbF6 are prepared. Their volume chemistry is discussed.
    Notes: Neu dargestellt wurden die Verbindungen MnSnF6 (a = 5,416 Å, c = 14,136 Å), FeSnF6 (a = 5,270 Å, c = 14,063 Å), ZnSnF6 (a = 5,216 Å, c = 13,801 Å), CoSnF6 (a = 5,211 Å, c = 13,933 Å), NiSnF6 (a = 5,152 Å, c = 13,763 Å), CuSnF6 (a = 5,13 Å, c = 13,82 Å), alle hex. LiSbF6-Typ, HgSnF6 (a = 5,321 Å, c = 15,027 Å) hex. VF3-Typ und CdSnF6 (a = 5,37Å, c = 14,47 Å) hex. VF3- oder LiSbF6-Typ. Die Raumchemie wird diskutiert.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19723920102
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  • 2
    Electronic Resource
    Electronic Resource
    Zur Kenntnis von Li2RhF6 (1974)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 405 (1974), S. 193-196 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On Li2RhF6New obtained Li2RhF6 (by high pressure fluorination) is a lemon yellow powder, very sensitive against moisture and probably thermodynamically instable under normal conditions. Li2RhF6 is isotypic with Na2SnF6, C2h5—P21/c, with a = 4.637; b = 4.634; c = 10,185 Å β = 117,1°, Z = 2. Calculated and observed powderdata (GUINIER-SIMON) have a good agreement.
    Notes: Durch Druckfluorierung [400 atm. F2] neu dargestellt wurde Li2RhF6, ein zitronengelbes Pulver, das gegen Feuchtigkeit bzw. Wasser äußerst empfindlich und vermutlich unter Normalbedingungen thermodynamisch instabil ist. Li2RhF6 ist isotyp mit Na2SnF6, C2h5—P21/c mit a = 4,637 Å b = 4,634 Å; c = 10,185 Å β = 117,1°, Z = 2. Berechnete und beobachtete Pulverdaten nach GUINIER-SIMON stimmen gut überein.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19744050209
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  • 3
    Electronic Resource
    Electronic Resource
    Über Neue Hexafluororhodate(IV): AIIRhIVF6 (AII = Ba, Sr, Ca, Mg, Zn, Cd, Hg, Ni sowie Cu) (1974)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 407 (1974), S. 13-22 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On Novel Hexafluoro Rhodates(IV): AIIRhIVF6. (AII = Ba, Sr, Ca, Mg, Zn, Cd, Hg, Ni, Cu)We obtained hithertoo unknown BaRhF6 and SrRhF6 (both lemon yellow) of (hexag.) BaSiF6-Type [a = 7.379, c = 7.211Å bzw. a = 7.157, c = 6.948 Å] as well as CaRhF6 (light yellow) [a = 5.267, c = 14.612 Å], MgRhF6 (light yellow) [a = 5.027, c 13.511Å], ZnRhF5 (light yellow) [a = 4.996, c = 13.683 Å], CdRhF6 (light yellow) [a = 5.,128 c = 14.447 Å], HgRhF6 (orange) [a = 5.133, c = 14.676 Å], NiRhF6 (light brown) [a = 4.960, c = 13.514 Å] all of (hexag.) LiSbF6-type. The strukture of CuRhF6 (light brown) is yet unknown.
    Notes: Neu dargestellt wurden BaRhF6 und SrRhF6, beide zitronengelb, (hexag.) BaSiF6-Typ [a = 7,379, c = 7,211 Å bzw. a = 7,157, c = 6,948 Å] sowie CaRhF6 (hellgelb) [a = 5,267, c = 14,612 Å], MgRhF6 (hellgelb) [a = 5,027, c = 13,511 Å], ZnRhF6 (hellgelb) [a = 4,996, c = 13,683 Å], CdRhF6 (hellgelb) [a = 5,128, c = 14,447 Å], HgRhF6 (orange) [a = 5,133, c = 14,676 Å], NiRhF6 (hellbraun) [a = 4,960, c = 13,514 Å], alle (hexag.) LiSbF6-Typ. Von CuRhF6 (hellbraun) ist die Struktur bislang unbekannt.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19744070103
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  • 4
    Electronic Resource
    Electronic Resource
    Zur Kenntnis der Hexafluororhodate(III): Über Cs2K[RhF6], Rb2K[RhF6], K2Na[RhF6], Rb2Na[RhF6] und Tl2Na[RhF6] (1975)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 414 (1975), S. 91-96 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the Knowledge of Hexafluororhodates(III): Cs2K[RhF6], Rb2K[RhF6], K2Na[RhF6], Rb2Na[RhF6] and Tl2Na[RhF6].New prepared are the compounds Cs2KRhF6 (a = 9.049 Å), Rb2NaRhF6 (a = 8.492 Å), Rb2KRhF6 (a = 8.876 Å), K2NaRhF6 (a = 8.362 Å) and Tl2NaRhF6 (a = 8.526 Å), all cubic Elpasoliths of pink colour. The Madelung-Part of lattice energy, MAPLE, is calculated and discussed.
    Notes: Neu dargestellt wurden Cs2KRhF6 (a = 9,049 Å), Rb2NaRhF6 (a = 8,492 Å), Rb2KRhF6 (a = 8,876 Å), K2NaRhF6 (a = 8,362 Å), und Tl2NaRhF6 (a = 8,526 Å), alle kubische Elpasolith-Vertreter, als rosafarbene Pulver. Der Madelunganteil der Gitterenergie, MAPLE, wird berechnet und diskutiert.
    Additional Material: 6 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19754140112
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  • 5
    Electronic Resource
    Electronic Resource
    Zur Kenntnis Neuer Hexafluoroplatinate(IV) (1975)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 414 (1975), S. 130-136 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On New Hexafluoroplatinates(IV)New prepared are PbPtF6 (light yellow), hex. BaGeF6-Type, [a = 7.227, c = 7.071 Å]; CaPtF6 (light yellow) [a = 5.245, c = 14.784 Å]; ZnPtF6 (light yellow) [a = 4.980, c = 13.828 Å]; CdPtF6 (light yellow) [a = 5.118, c = 14.623 Å]; HgPtF6 (light yellow) [5.132, c = 14.814 Å]; MnPtF6 (ocker) [a = 5.094, c = 14.231 Å], CoPtF6 (light brown) [a = 5.002, c = 13.815 Å]; NiPtF6 (egg yellow) [a = 4,937, c = 13.687Å], all these of hex. LiSbF6-structure. The structure of CuPtF6 (light yellow) is yet unknown.
    Notes: Nou dargestellt wurden PbPtF6 (hellgelb), hex. BaGeF6-Typ, [a = 7,227, c = 7,071 Å]; CaPtF6 (hellgelb) [a = 5,245, c = 14,784 Å]; ZnPtF6 (hellgelb) [a = 4,980, c = 13,828 Å], CdPtF6 (hellgelb) [a = 5,118, c = 14,623 Å], HgPtF6 (hellgelb) [a = 5,132, c = 14,814 Å], MnPtF6 (ocker) [a = 5,094, c = 14,231 Å], CoPtF6 (hellbraun) (a = 5,002, c = 13,815 Å); NiPtF6 (eigelb) [a = 4,937, c = 13,687 Å], diese kristallisieren hexagonal im LiSbF6-Typ. Von CuPtF6 (hellgelb) ist die Struktur bislang unbekannt.
    Additional Material: 12 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19754140204
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