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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 361 (1968), S. 249-253 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Be, Ca, Sr, MnII, CoII, NiII, CuII and UO2+2 trichloracetates of the general composition M(CCl3CO2)2 were prepared from the nitrates. Solvates with tetrahydrofuran, 1,4-dioxane, pyridine, and methanol were decomposed at low temperature and pressure. The solvates as well as the non-solvated trichloroacetates were investigated in view of their decarboxylation.
    Notes: Beryllium-, Calcium-, Strontium-, Mangan-, Kobalt-, Nickel-, Kupfer- und Uranyltrichloracetate der allgemeinen Zusammensetzung: M(CCl3CO2)2 wurden aus den Nitraten dargestellt. Solvate mit Tetrahydrofuran, 1, 4-Dioxan, Pyridin und Methanol wurden bei niedrigen Temperaturen und Drucken zerlegt. Solvate sowie nichtsolvatisierte Trichloracetate wurden im Hinblick auf ihre Decarboxylierung untersucht.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 374 (1970), S. 77-85 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Die Decarboxylierung des Trichloracetations in basischen Lösungsmitteln ergibt als Zwischenstufe das Trichlorcarbanion, das in Chlorid und Dichlorcarben zerfallen oder sich mit einem Proton zu Chloroform vereinigen kann. Die Bedingungen, unter denen die Protonierung vorherrscht, wurden untersucht zwecks möglicher Anwendung der Reaktion für die Synthese von Metallverbindungen in nichtwäßrigen Lösungsmitteln.
    Notes: The decarboxylation of trichloroacetate ion in basic solvents produces the intermediate trichlorocarbanion which may split into chloride and dichlorocarbene or combine with a proton to chloroform. Conditions under which protonation predominates were examined for possible use of the reaction for synthesizing metal compounds in non-aqueous solvents.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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