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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 348 (1966), S. 257-260 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The crystal structure of the modification of TiBr4 stable at 20°C has been determined by X-ray methods. Its lattice is monoclinic, space group C2h5=P 21/c, with \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm a}_0 \, = \,10.17\,{\rm {\AA}};\,\,\,{\rm b}_{\rm 0} \, = \,7.09\,{\rm {\AA}};\,\,\,\,{\rm c}_{\rm 0} \, = \,10.41\,{\rm {\AA}};\,\,\beta \, = \,101^ \circ 58' $$\end{document}.The structure is an isotype of that of SnBr4.
    Notes: Die Kristallstruktur der bei 20°C stabilen Modifikation des TiBr4 wurde röntgenographisch untersucht. Sie ist monoklin, Raumgruppe C2h5—P 21/c, mit den Gitterkonstanten \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm a}_0 \, = \,10,17\,{\rm {\AA}};\,\,\,{\rm b}_{\rm 0} \, = \,7,09\,{\rm {\AA}};\,\,\,\,{\rm c}_{\rm 0} \, = \,10,41\,{\rm {\AA}};\,\,\beta \, = \,101^ \circ 58' $$\end{document}.Die Kristallstruktur ist der des SnBr4 isotyp.
    Additional Material: 1 Tab.
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 421 (1976), S. 15-23 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Cyanonitrosylferrates and Cyanocarbonylnitrosylferrates of Low Oxidation StatesBy the reduction of sodium nitroprusside with alkali metals in liquid ammonia the cyanonitrosylferrates [Fe[CN]5, NO]3-, [Fe(CN)4, NO]2-, [Fe(CN)4N0]3- and [Fe(CN)3N0]4- are formed. Preparation and properties of these reduction products (Table 1) and of the cyanocarbonylnitrosylferrates still missing within the series [Fe(CN)n(CO)3-nNO](n+l)- (n = 1 and 2) are described. Structure and bonding of these complexes are discussed with respect to their magnetic properties and their i.r. spectra.
    Notes: Bei der Reduktion von Nitroprussidnatrium durch Alkalimetalle in fl. Ammoniak werden die Cyanonitrosylferrat-Ionen [Fe(CN)5NO]3-, [Fe(CN)4NO]2-, [Fe(CN)4NO]3- und [Fe(CN)3NO]4- gebildet. Darstellung und Eigenschaften dieser Reduktionsprodukte (Tab. 1) sowie der noch fehlenden Cyanocarbonylnitrosylferrate der Reihe [Fe(CN)n(CO)3-nNO](n+1)- (n = 1 und 2) werden beschrieben. Struktur und Bindungen dieser Komplexe werden anhand ihrer magnetischen Eigenschaften und ihrer IR-Spektren diskutiert.
    Additional Material: 1 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 578 (1989), S. 81-88 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On Phosphole Complexes of 3d Transition MetalsThe 2-ethoxy-, 2-cyclohexanoxy-, 2-phenoxy-, 2-(4′-methylphenoxy)- and 2-(4′-chlorphenoxy)-benzo[1,3,2]-dioxaphospholcomplexes of chromium(III), iron(II), cobalt(II), and nickel(II) are synthesized and characterized by N.M.R., I.R. and U.V.-VIS spectroscopy and by magnetic investigations. When titanium(IV) ore copper(II) halides are used redox-reactions can be observed. The corresponding copper(I) complexes are isolated.
    Notes: Es werden 2-Ethoxy-, 2-Cyclohexanoxy-, 2-Phenoxy-, 2-(4′-Methylphenoxy)- und 2-(4′-Chlorphenoxy)benzo[1,3,2]dioxaphospholkomplexe des Chrom(III), Eisen(II), Cobalt(II) und Nickel(II) synthetisiert und mittels NMR-, IR- und UV-VIS-Spektroskopie sowie durch magnetische Untersuchungen charakterisiert. Im Falle des Titan(IV) und des Kupfer(II) werden Redoxreaktionen beobachtet, es werden entsprechende Kupfer(I)-Komplexe isoliert und im Falle des 2-(4′-Chlorphenoxy)-benzol[1,3,2]dioxaphospholliganden der Kupfer(II)-Komplex nachgewiesen.
    Additional Material: 2 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 13 (1880), S. 2342-2345 
    ISSN: 0365-9496
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 14 (1881), S. 574-576 
    ISSN: 0365-9496
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 14 (1881), S. 1459-1461 
    ISSN: 0365-9496
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 14 (1881), S. 1848-1851 
    ISSN: 0365-9496
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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