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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 96 (1916), S. 317-352 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 25 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 53 (1907), S. 338-343 
    ISSN: 0863-1778
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Spectroscopic Studies on Sulphur Compounds. VII. 1H- and 13C-NMR Spectroscopic Investigations of Sulphinic Acid Chlorides and Chloro-sulphurous Acid AlkylestersThe temperature dependent 1H- and 13C-n.m.r. spectra of the sulphinic acid chlorides R - S(O)Cl and of the chloro-sulphurous acid alkylesters RO - S(O)Cl with R = CH3CH2- and (CH3)2CH- have been measured. The differing behaviour of both nuclei is discussed in terms of inversion at the chiral sulphur atom.
    Notes: Von den Sulfinsäurechloriden R - S(O)Cl und den Chloroschwefligsäure-alkylestern RO - S(O)Cl mit R = CH3CH2- und (CH3)2CH- wurden die temperaturabhängigen 1H- und 13C-NMR-Spektren aufgenommen. Die dabei auftretenden unterschiedlichen Verhaltensweisen der beiden Kerne werden als Folge einer Inversionsbewegung am Chiralitätszentrum Schwefelatom diskutiert.
    Additional Material: 5 Tab.
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 420 (1976), S. 51-54 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The Crystal and Molecular Structure of N,N′-Bis(trimethylsilyl) Oximidic Acid Bis (trimethylsilyl) EsterThe X-ray structure analysis of the reaction product of oxalyl chloride with sodium bis(trimethylsilyl) amide formulated by PUMP and ROCHOW as N,N′-bis(trimethylsilyl) oximidic Acid bis (trimethylsilyl) ester shows that the suggested structure is correct for the solid state. The compound crystallizes in the space group P1 with a = 9.948(4), b = 6.612(3), c = 10.370(4) Å, α = 88.87(6), β = 116.95(4), γ = 98.23(6)°, and Z = 1. The molecule manifests symmetry 1.
    Notes: Die Röntgenstrukturanalyse des von PUMP und ROCHOW als N,N′-Bis(trimethylsilyl)-oximidsäure-bis(trimethylsilyl)-ester formulierten Reaktionsprodukts von Oxalylchlorid mit Natrium-bis(trimethylsilyl)-amid zeigt, daß diese Formulierung für den festen Zustand zutrifft. Die Verbindung kristallisiert in der Raumgruppe P1 mit a = 9,948(4), b = 6,612(3), c = 10,370(4) Å, α = 88,87(6), β = 116,95(4), γ = 98,23(6)° und Z = 1. Die Molekel besitzt die Eigensymmetrie 1.
    Additional Material: 1 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 420 (1976), S. 55-64 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Spectroscopic Studies on Sulphur Compounds. VI. On Silyl Tautomerism in Bis-trimethylsilylated Sulphinic AmidesThe bis-trimethylsilylated sulphinic amides 1 and 2 (eq. 1) as well as the sulphenic amide 4 (eq. 2) have been prepared for the first time and their structures deduced from lH n.m.r., 29Si n.m.r., i.r., and mass spectra. The imidate structure B (scheme 1) has been assigned unequivocally to compounds 1 and 2. The same structure is suggested for the known compound 3 on the basis of its spectroscopic behaviour. 29Si n.m.r. spectra are recorded for several reference compounds.
    Notes: Die zweifach trimethylsilylsubstituierten Sulfinamide 1 und 2 (Gl. 1) sowie das Sulfenamid 4 (Gl. 2) wurden erstmalig dargestellt und über 1H-NMR-, 29Si-NMR-, IR-und Massenspektren charakterisiert. Demnach liegen die Verbindungen 1 und 2 eindeutig, die bereits bekannte Verbindung 3 mit hoher Wahrscheinlichkeit in der N,O-silylsubstituierten Imidform B (Schema 1) vor. Die 29Si-NMR-Spektren einer Reihe von Vergleichssubstanzen werden mitgeteilt.
    Additional Material: 3 Tab.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 443 (1978), S. 185-188 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Structure of N, N′-Bis (trimethylsilyl) DithiooxamideAn X-ray analysis of a compound prepared by WALTER et al. and formulated as N, N′-bis(trimethylsily1) dithiooxamide proves that the suggested structure is correct for the solid state. The compound crystallizes in the orthorhombic space group Pbcn with lattice constants a = 10.702, b = 12.485, c = 11.733 Å and Z = 4. The molecular symmetry is 1.
    Notes: Die Röntgenstrukturanalyse der von WALTER u. Mitarb. dargestellten und als N, N′-Bis(trimethylsilyl)-dithiooxamid formulierten Verbindung ergibt, daß diese Formulierung für den festen Zustand zutrifft. Die Verbindung kristallisiert in der orthorhombischen Raum-gruppe Pbcn mit den Gitterkonstanten a = 10,702, b = 12,485, c = 11,733 Å und Z = 4. Die Mole-krl besitzt die kristallographische Eigensymmetrie 1.
    Additional Material: 1 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 6 (1873), S. 386-389 
    ISSN: 0365-9496
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 6 (1873), S. 389-390 
    ISSN: 0365-9496
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 12 (1879), S. 1323-1326 
    ISSN: 0365-9496
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 7 (1874), S. 869-872 
    ISSN: 0365-9496
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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