ISSN:
0044-2313
Keywords:
Lithium iodide
;
DME complex
;
synthesis
;
crystal structure
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Synthesis and Crystal Structure of [Li(DME)2I].LiI can be dissolved at 50°C in toluene/DME (2:1). At - 20°C [Li(DME)2I] (1) was isolated in 75% yield. 1 was characterized by NMR techniques as well as an X-Ray structure determination. 1 crystallizes in the space group C2/c with a = 1 356.9(2), b = 813.2(1), c = 1 259.1(2) pm, and β = 99.74(1)°.
Notes:
LiI kann bei 50°C in Toluol/DME (2:1) in Lösung gebracht werden. Bei - 20°C wird [Li(DME)2I] (1) in 75% Ausbeute isoliert. 1 wurde mittels NMR-Spektroskopie sowie durch eine Röntgenstrukturanalyse charakterisiert. 1 kristallisiert in der Raumgruppe C2/c mit a = 1 356,9(2), b = 813,2(1), c = 1 259,1(2) pm und β = 99,74(1)°.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19936191008
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