ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Es wurden zwei isomere (α und β-) Reihen von Hydridokomplexen des Iridiums mit Methyldiphenylarsin, IrHX2(Ph2AsMe)3 (X = Cl, Br oder I), dargestellt und untersucht. Zum Vergleich wurden auch die entsprechenden Trihalogenokomplexe IrX3(Ph2AsMe)3 dargestellt. Hydridokomplexe des Rhodiums, RhHX2(Ph2AsMe)3, wurden nach einer neuen Methode erhalten.
Notes:
Two isomeric series (α and β) of hydrido complexes of iridium with methyldiphenyl arsine of the general formula IrHX2(Ph2AsMe)3 (X = Cl, Br or I) have been prepared and characterised. The α compounds are prepared by reacting the metal halide and the arsine in alcoholic medium with zinc and the corresponding halogen acid, while the β compounds are prepared by refluxing the metal halide and the arsine in alcoholic medium in presence of potassium hydroxide. The properties of these hydrido complexes are compared with the corresponding trihalogeno complexes of the general formula IrX3(Ph2AsMe)3. Hydrides of rhodium of the general formula RhHX2(Ph2AsMe)3, prepared earlier using hypophosphorous acid as reducing agent, can be made by other methods.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19683620512
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