ISSN:
0009-2940
Keywords:
Ketenes (dimeric)
;
reactions with nucleophiles and electrophiles
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The title lactone 2 acylates a variety of amines including phenylalanine, sterically hindered alcohols, and phenols. With activated non-enolizable carbonyl compounds, bis-spiro 6-membered β-keto lactones are formed. Oxidative rearrangement of 2 affords bis-spiro lactones 12 and 13.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19941270716
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