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  • Inorganic Chemistry  (1)
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    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 401 (1973), S. 15-20 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: New Compounds of NaxPt3O4 Structural TypeNew members of the NaxPt3O4-type platinates MexPt3O4 (Me = Li, K, Ca, Ba, Co, Zn and Cd; 0 〈 x 〈 1) are prepared by solid state reactions in air and characterized by their lattice constants. Investigations of thermal stability by means of thermogravimetry and differential thermal analysis of the new and of known platinates and palladates of this structure type are reported. The thermolysis of the palladates starts at 844-1020°C and of the platinates at 705-798°C. The decomposition leads to platinum metal and binary oxide or to more stable palladates or platinates.
    Notes: Neue Platinate MexPt3O4 (Me = Li, K, Ca, Ba, Co, Zn und Cd; 0 〈 x 〈 1) werden durch Festkörperreaktionen an Luft hergestellt und durch ihre Gitterkonstanten charakterisiert. Die neuen Platinate sowie die bekannten Platinate und Palladate dieses Strukturtyps werden hinsichtlich ihrer thermischen Beständigkeit mittels Thermogravimetrie und Differentialthermoanalyse untersucht. Die Palladate beginnen bei 844-1020°C zu zerfallen, die Platinate bei 705-798°C. Bei der Zersetzung entstehen Gemische aus Platinmetall und binärem Oxid oder stabilere Palladate, bzw. Platinate.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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