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  • General Chemistry  (8)
  • Inorganic Chemistry  (7)
  • 61.40  (3)
  • STRUCTURAL MECHANICS  (3)
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  • 1
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    In:  CASI
    Publication Date: 2016-06-07
    Description: Apollo project - progress and national benefits
    Keywords: STRUCTURAL MECHANICS
    Type: Proceedings of the Fourth National Conference on the Peaceful Uses of Space; NASA-SP-51
    Format: application/pdf
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  • 2
    Publication Date: 2019-06-27
    Description: Structural mechanics of deformation and fracture - responses of model viscoelastic materials to impact
    Keywords: STRUCTURAL MECHANICS
    Type: NASA-CR-80918
    Format: application/pdf
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  • 3
    Publication Date: 2019-06-27
    Description: Mechanical behavior of materials with temperature dependent viscosity, using electric analogy on nonlinear Maxwell model
    Keywords: STRUCTURAL MECHANICS
    Type: ; ACE(
    Format: text
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 52 (1991), S. 335-338 
    ISSN: 1432-0630
    Keywords: 61.40 ; 61.80 ; 72.20
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract n-type a-Si:H films have been irradiated with light, electrons, protons and heavy ion beams. It is shown that the non-thermal creation of dangling-bond defects activates significant densities of previously inactive phosphorus dopants. The relevance of these results is discussed with respect to equilibration phenomena in doped material and with respect to degradation phenomena in a-Si:H solar cells.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 53 (1991), S. 235-240 
    ISSN: 1432-0630
    Keywords: 61.40 ; 61.80 ; 72.20
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Hydrogenated amorphous silicon (a-Si:H) films have been irradiated with H+, B+, P+, and Ar+ ion beams. The accumulation and the annealing of irradiation-induced defects has been investigated through a series of electronic transport and PDS measurements. We find that for all projectiles damage accumulation is dominated by atomic displacement collisions with the damage saturating for energy transfers in excess of about 10 eV/target atom. Annealing at elevated temperatures causes the conductivity of doped and irradiated a-Si:H films to increase according to stretched exponential decay curves. All annealing parameters derivable from such fits scale with the energy originally dissipated into atomic displacement collisions. For energy transfers up to 10 eV/target atom the activation energy for annealing increases up to a saturation value and, at the same time, an increasing fraction of the irradiation-induced defects becomes stable against annealing at moderate temperatures (T a〈250° C). We discuss these results with respect to damage accumulation data in crystalline silicon (c-Si) and with regard to the annealing of metastable defects in a-Si:H.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 54 (1992), S. 40-46 
    ISSN: 1432-0630
    Keywords: 61.40 ; 71.55 ; 82.60
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Amorphous (a-) semiconductors like a-Si:H and the chalcogenide glasses possess a general tendency to establish an overall equilibrium between the electronic system and the lattice with its dopant and defect sites. In the present paper the chemical interactions which establish these equilibria within the bulk of the a-semiconductor lattices are compared to chemical interactions in liquid electrolytes, particularly to those in H2O. These considerations reveal close similarities between autocompensation doping in a-semiconductors and acid/base reactions in H2O. The effects of light and field-effect induced defect formation, on the other hand, are shown to be related to the phenomenon of electrolysis in H2O. The consideration of these analogies further emphasizes the roles of charge-carrier localization and that of H-diffusion in promoting dopant and defect equilibration reactions in a-semiconductors.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 416 (1975), S. 256-262 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Structure and Vibrational Spectra of Trioxodifluoromolybdates(NH4)2MoO3F2 crystallizes in the space group P212121 with a = 6.361(1); b = 7.488(1), c = 11.103(2) Å and Z = 4. According to a threedimensional X-ray structure analysis (596 reflections, R = 0.066) the polymer MoO3F22--ion consists of planar cis-dioxodifluoro units which are linked into an infinite chain by alternating short (1.880 Å) and long (2.007 Å) Mo—O bonds. The vibrational spectra of (NH4)2MoO3F2 and K2MoO3F2. H2O are discussed.
    Notes: (NH4)2MoO3F2 kristallisiert in der Raumgruppe P212121 mit a = 6,361(1) b = 7,488(1), c = 11,103(2) Å und Z = 4. Nach dem Ergebnis einer dreidimensionalen Röntgenstrukturanalyse (596 Reflexe, R = 0,066) liegen im MoO3F22--Ion planare cis-dioxodifluoro- Gruppen vor, die senkrecht dazu über alternierend kurze (1,880 Å) und lange (2,007 Å) Mo-O-Brückenbindungen zu unendlichen Ketten verknüpft sind. Die Schwingungsspektren von (NH4)2MoO3F2 und K2MoO3F2. H2O wurden registriert und zugeordnet.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 462 (1980), S. 152-158 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Investigations on the Coordination Chemistry of Zinc Dialkyls. XIV. On Lithium and Zinc 3(N, N-Dialkylamino)propyl CompoundsIt is reported on synthesis and properties of organo lithium compounds of the type [R2NCH2CH2CH2Li]n. The structure is proposed by reason of molecular weight determination and 13C-NMR spectra.In dependence of the molar ratio the lithium dialkylamino propyls and the corresponding Grignard reagents react with zinc chloride forming dimer alkyl zinc chlorides [R2NCH2CH2CH2ZnCl]2 or monomer spiranoide chelate complexes of the formula [R2NCH2CH2CH2]2Zn (R = CH3, C2H5).
    Notes: Es wird über die Synthese und die Eigenschaften von Organolithium-verbindungen des Typs [R2NCH2CH2CH2Li]n berichtet und ein Strukturvorschlag aufgrund von Molmassebestimmungen und 13C-NMR-Spektren unterbreitet.Die Lithium-dialkylaminopropyle sowie die entsprechenden Grignardverbindungen reagieren mit Zinkchlorid je nach Molverhältnis der Reaktionspartner zu dimeren Alkylzinkchloriden [R2NCH2CH2CH2ZnCl]2 bzw. monomeren, teilweise schon bekannten, spiranoiden Innerkomplexen der Formel [R2NCH2CH2CH2]2Zn (R = CH3. C2H5).
    Additional Material: 1 Tab.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 51 (1938), S. 466-471 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 11 Tab.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 357 (1968), S. 172-176 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Experiments for preparing hexachlorotitanates by reaction of TiCl4 with alkali chlorides or calcium chloride in pressure bombs at 550-750°C are described. Pure K2TiCl6 and Cs2TiCl6 were obtained, whereas the reaction products from LiCl, NaCl and CaCl2 contained not more than 4 to 6.5 weight per cent of titanium. A content of up to 0.24 weight per cent trivalent titanium is found at higher temperatures resulting from evolution of elemental chlorine from the titanium tetrachloride.
    Notes: Es werden Versuche zur Darstellung von Hexachlorotitanaten aus TiCl4 und Alkalichlorid oder Calciumchlorid in Druckbomben bei Temperaturen von 550-750°C beschrieben. K2TiCl6 und Cs2TiCl6 können dabei rein und wasserfrei erhalten werden, während mit LiCl, NaCl und CaCl2 nur Produkte mit Titangehalten von max. 4 bis 6,5 Gew.-% entstehen. Mit steigender Versuchstemperatur treten in den Präparaten durch Cl2-Abspaltung aus dem TiCl4 entstandene Gehalte an dreiwertigem Titan auf, die bis zu 0,24 Gew.-% betragen können.
    Additional Material: 2 Tab.
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