ISSN:
0009-2940
Schlagwort(e):
Stereoselectivity, destructive
;
Phosphite oxidation
;
Oxaziridines, chiral
;
Chemistry
;
Inorganic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
Asymmetric Synthesis of Chiral Phosphorus Compounds by Destructive-Selective Oxidation of P(III) Compounds by Means of Chiral OxaziridinesFrom camphor and fenchone chiral N -sulfonyloxaziridines (e.g, 7,13) are available that are well-suited for the destructive-stereoselective oxidation of P(III) compounds 16. Optimum reagents and reaction conditions for this oxidation are determined by a systematic study. Chiral P(III) and P(V) compounds can thus be prepared from racemic P(III) derivatives.
Zusätzliches Material:
2 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/cber.19911240725
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