ISSN:
0009-2940
Keywords:
Iminophosphines
;
s̰-Push-pull substitution
;
Nitrogen inversion
;
cis/trans Isomerization
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A combination of α-electron-withdrawing/-releasing substituents (push-pull substitution) at iminophosphanes considerably lengthen (shorten) the central PN bond as revealed by ab initio calculations on model geometries; they also stress the importance of the energy barrier to inversion at nitrogen.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19901230811
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