ISSN:
0009-2940
Keywords:
Pyrrolic nickel(II) complexes
;
Imine hydrolysis
;
Template effect
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
(2-Pyrrolylmethane)(2-pyrrolylmethyl)imine (2) and an equimolar amount of 2-formylpyrrole give, in the presence of nickel(II) in hot methanol, the novel tripyrrolic nickel(II) complex [SP-4]-[(2-dipyrrinato-k2N,N′-methyl)(2-pyrrolylmethenato- kN′′)imine-kN′′′]nickel(II) (4). This planar complex has been characterized by X-ray crystallography, a mechanism for its formation is proposed and its mass spectral behavior is discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19961291009
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