Publication Date:
2019-08-28
Description:
The kinetics of the reactions CH3 + HBr, CD3 + HBr, CH3 + DBr, C2H5 + HBr, C2H5 + DBr, t-C4H9 + HBr, and t-C4H9 + DBr is studied as a function of temperature (257-430 K) and pressure (10-300 Torr of N2). Time-resolved resonance fluorescence detection of Br atom appearance following laser flash photolysis of RI was used in the experiments. Results show that the rates of all reactions increased as the temperature decreased.
Keywords:
INORGANIC AND PHYSICAL CHEMISTRY
Type:
Journal of Physical Chemistry (ISSN 0022-3654); 95; 24; p. 9890-9896.
Format:
text
Permalink