ALBERT

Description: As a part of our research to better understand magmatic processes in the Eucrite Parent Body, we have initiated an ambitious program of study of major, minor and trace elements in orthopyroxene from diogenites. This paper reports preliminary results for major and minor elements in orthopyroxenes for a suite of 13 diogenites: Aioun El Atrouss, ALH 84001, ALH A 77256, EET 87530, Ellemeet, Garland, Ibbenburen, Johnstown, Manegoan, peckelsheim, Roda, Shalka, and Tatahouine. A companion paper by Shearer et al. reports new trace element data for ALH 84001, ALH A 77256, Ibbenburen, and Tatahouine. We have presently collected over 800 high quality pyroxene microprobe analyses for Si, Al, Ca, Na, Mn, Fe, Mg, Cr, and Ti. The chemical systematics observed for these orthopyroxenes reflect original magmatic mineral/melt partitioning plus later trapped liquid/mineral equilibration, subsolids, exsolution, and mineral/mineral metamorphic reactions. We have therefore avoided, at this point, any attempt to use statistical analysis to group (e.g. factor or cluster analysis) these orthopyroxenes chemically.

Description: Eucrite, howardite, and diogenite members of the achondrites are considered, by many, to be genetically related. Therefore, each provide a piece of the puzzle for reconstructing magmatic processes on the eucrite parent body (EPB). The relationship between eucrites and diogenites can be viewed within the context of two distinctly different models: (1) fractional crystallization; and (2) partial melting. In fractional crystallization models, eucrites and diogenites represent a complementary continuum of planetary fractional crystallization products in which the diogenites represent crystal accumulations during the crystallization of eucritic magmas at shallow to deep levels in the EPB. Alternatively, experimental studies may be interpreted as indicating eucrites represent peritectic partial melts of a primitive, chondritic EPB mantle. Within this type of model, the diogenites are also generally considered to be cumulates; however, their petrogenetic relationship to the eucrites is less clear. Sack et al. proposed that the olivine diogenites represent residua from the partial melting events that produced eucritic liquids. Initial trace element studies of orthopyroxene (OPX) are consistent with this model. However, this trace element modeling of the olivine diogenites is nonunique. As a further test of these models, we did the following three things: (1) analyzed OPX from cumulate diogenites to compare with the olibine diogenite data; (2) improved ion microprobe analytical techniques for the analysis of elements critical to our interpretations; and (3) selected more relevant Kd's for OPX-eucritic melt.

Description: The very low Ti green glasses from the Apollo 15 site have intrigued scientists for over 20 years. Their primitive composition has been used to understand magmatic processes and the structure of the moon. The compositional variability observed in the Apollo 15 glass population has long been a point of debate. Initial studies did not recognize the compositional diversity in the glasses. Stolper et al. documented the major element variability and concluded it could not be produced by magmatic processes and therefore concluded that these glasses must be of impact origin. Subsequent studies confirmed a volcanic origin for the glass population and attempted to elucidate magmatic processes to account for its compositional variability. Models that have been proposed for these glasses include the following: (1) the crystallization of single or multiple phases (olivine, pyroxene, Fe metal, immiscible sulfide); (2) the incompatible behavior of Ni and Co during multiple phase crystallization at extremely low fO2; and (3) magma or source mixing. All of these models have problems. Type (1) models appear not to be consistent with recent trace element studies on the glasses; model (2) is dependent on the debatable incompatible behavior of Ni and Co, and, in models of type (3), the origin and nature of mixing models are somewhat unconstrained. This study compares the Apollo 15 green glasses with the very low Ti picritic glasses from other landing sites.