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  • INORGANIC AND PHYSICAL CHEMISTRY  (2)
  • INSTRUMENTATION AND PHOTOGRAPHY  (2)
  • 1
    Publication Date: 2011-08-19
    Keywords: INSTRUMENTATION AND PHOTOGRAPHY
    Type: AIAA Journal (ISSN 0001-1452); 27; 1074-108
    Format: text
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  • 2
    Publication Date: 2013-08-31
    Description: Previously we have reported carbonate liq./silicate liq. partition coefficients (D) for a standard suite of trace elements (Nb, Mo, Ba, Ce, Pb, Th, and U) and Ra and Pa as well. In brief, we have found that immiscible liquid partitioning is a strong function of temperature. As the critical temperature of the carbonate-silicate solvus is approached, all partition coefficients approach unity. Additionally, for the overwhelming majority of the partitioning elements, InD is a linear function of 'ionic field strength,' z/r, where z is the charge of the partitioned cation and r is its ionic radius.
    Keywords: INORGANIC AND PHYSICAL CHEMISTRY
    Type: Lunar and Planetary Inst., Twenty-Fourth Lunar and Planetary Science Conference. Part 2: G-M; p 733-734
    Format: application/pdf
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  • 3
    Publication Date: 2019-06-28
    Description: The performance of two constant-temperature normal hot-wire techniques in a supersonic flow is examined. The first technique uses a single-wire and rapid scanning of multiple overheat ratios. Time averages of the signals at all overheats are used to separate the mean and rms mass flux, stagnation temperature and their cross-correlation. The second technique uses a dual-wire probe with each wire operating at different overheat ratios, giving instantaneous mass flux and stagnation temperature. Preliminary results indicate that the separation distance (0.18 mm) between the two hot wires in the dual-wire probe does not introduce significant error. However, the rms mass flux inferred from the dual-wire technique is a factor of two higher than that from the single-wire technique.
    Keywords: INSTRUMENTATION AND PHOTOGRAPHY
    Type: AIAA PAPER 88-0422
    Format: text
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  • 4
    Publication Date: 2019-07-13
    Description: Experiments were carried out to evaluate the Soret effect in liquid Fe-Ni-S-P alloys in order to gain a better understanding of the physical and thermodynamic properties of metallic liquids and to assess the possibility of systematic errors in Czochralski growth techniques. The metal-sulfide liquids were found to show a substantial Soret effect and, contrary to previous expectation, can be as large as that seen in the silicate system. The segregation is largely produced by S-Fe interactions. The P redistribution occurs to reduce activity gradients in P consequent upon S gradients, and P segregation can be approximately predicted in Fe-Ni-S liquids using the activity model of Jones and Malvin (1990). It is inferred that the sense of the Soret segregation, with P going to the cold end and S going to the hot end, is in accordance with the prediction of Malvin et al. (1986), who speculated that the crystal-pulling experiments of Sellamuthu and Goldstein (1985) was influenced by the Soret effect.
    Keywords: INORGANIC AND PHYSICAL CHEMISTRY
    Type: Lunar and Planetary Science Conference; Mar 12, 1990 - Mar 16, 1990; Houston, TX; United States
    Format: text
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