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  • 1
    Publication Date: 2011-08-20
    Description: Hydroxyl radicals (OH) are a key species in atmospheric photochemistry. In the lower atmosphere, up to ~30% of the primary OH radical production is attributed to the photolysis of nitrous acid (HONO), and field observations suggest a large missing source of HONO. We show that soil nitrite can release HONO and explain the reported strength and diurnal variation of the missing source. Fertilized soils with low pH appear to be particularly strong sources of HONO and OH. Thus, agricultural activities and land-use changes may strongly influence the oxidizing capacity of the atmosphere. Because of the widespread occurrence of nitrite-producing microbes, the release of HONO from soil may also be important in natural environments, including forests and boreal regions.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Su, Hang -- Cheng, Yafang -- Oswald, Robert -- Behrendt, Thomas -- Trebs, Ivonne -- Meixner, Franz X -- Andreae, Meinrat O -- Cheng, Peng -- Zhang, Yuanhang -- Poschl, Ulrich -- New York, N.Y. -- Science. 2011 Sep 16;333(6049):1616-8. doi: 10.1126/science.1207687. Epub 2011 Aug 18.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Biogeochemistry Department, Max Planck Institute for Chemistry, Mainz 55020, Germany. h.su@mpic.de〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/21852453" target="_blank"〉PubMed〈/a〉
    Keywords: Agriculture ; Atmosphere/*chemistry ; Circadian Rhythm ; Hydrogen-Ion Concentration ; Hydroxyl Radical/*analysis/chemistry ; Nitrites/*chemistry/*metabolism ; Nitrous Acid/*analysis/chemistry ; Oxidation-Reduction ; Photolysis ; Soil/*chemistry ; *Soil Microbiology
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 2
    Publication Date: 2015-04-11
    Description: Ocean acidification triggered by Siberian Trap volcanism was a possible kill mechanism for the Permo-Triassic Boundary mass extinction, but direct evidence for an acidification event is lacking. We present a high-resolution seawater pH record across this interval, using boron isotope data combined with a quantitative modeling approach. In the latest Permian, increased ocean alkalinity primed the Earth system with a low level of atmospheric CO2 and a high ocean buffering capacity. The first phase of extinction was coincident with a slow injection of carbon into the atmosphere, and ocean pH remained stable. During the second extinction pulse, however, a rapid and large injection of carbon caused an abrupt acidification event that drove the preferential loss of heavily calcified marine biota.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Clarkson, M O -- Kasemann, S A -- Wood, R A -- Lenton, T M -- Daines, S J -- Richoz, S -- Ohnemueller, F -- Meixner, A -- Poulton, S W -- Tipper, E T -- New York, N.Y. -- Science. 2015 Apr 10;348(6231):229-32. doi: 10.1126/science.aaa0193.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉School of Geosciences, University of Edinburgh, West Mains Road, Edinburgh EH9 3FE, UK. matthew.clarkson@otago.ac.nz. ; Faculty of Geosciences and MARUM-Center for Marine Environmental Sciences, University of Bremen, 28334 Bremen, Germany. ; School of Geosciences, University of Edinburgh, West Mains Road, Edinburgh EH9 3FE, UK. ; College of Life and Environmental Sciences, University of Exeter, Laver Building, North Parks Road, Exeter EX4 4QE, UK. ; Institute of Earth Sciences, NAWI Graz, University of Graz, Heinrichstrasse 26, 8010 Graz, Austria. ; School of Earth and Environment, University of Leeds, Leeds LS2 9JT, UK. ; Department of Earth Sciences, University of Cambridge, Downing Street, Cambridge CB2 3EQ, UK.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/25859043" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; *Aquatic Organisms ; Atmosphere ; Boron ; *Carbon ; Carbon Cycle ; Carbon Isotopes ; Ecosystem ; *Extinction, Biological ; Hydrogen-Ion Concentration ; Isotopes ; Oceans and Seas ; Seawater/*chemistry ; Time
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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