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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 32 (1983), S. 95-104 
    ISSN: 1572-9613
    Keywords: Hard spheres ; crystallization ; random close packing ; virial expansion ; Padé approximants
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract An exhaustive Padé approximant study of the Mayer virial series expansion is carried out for the classical hard-sphere system. As one increases the order of the different approximants a clear tendency is seen to reproduce both the random close packing divergence of the fluid branch as well as its instability (towards the crystalline phase) at the spinodal point.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Interface science 2 (1994), S. 183-191 
    ISSN: 1573-2746
    Keywords: Grain growth ; triple junctions ; topological effects on grain growth ; von Neumann-Mullins equation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract In addition to driving forces due to curvature of grain boundaries there are driving forces acting on triple junctions which also contribute to grain growth. Equations are derived for the rate of change, due to the triple junction forces, of the average area or average volume of 2D and 3D grains, respectively, with a fixed number of topological elements (edges in 2D and faces in 3D). The equations derived are compared with the von Neumann-Mullins equation for 2D curvature driven grain growth and to the extension of that equation to 3D grain growth. In triple junction controlled grain growth, the effect ofn orF is qualitatively the same as in curvature driven growth, with a threshold atn or −F between shrinkage and growth. However, the rates are in general not linear onn orF, and there is a size effect which has a repercursion on the overall growth kinetics.
    Type of Medium: Electronic Resource
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