ISSN:
1434-1948
Keywords:
Isoquinoline
;
Lithium
;
Self-condensation
;
Solid-state structure
;
Solution structure
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The product of reaction between ortho-methylbenzonitrile (o-MeC6H4CN) and lithium N,N,N′-trimethylethylene-diamide [LiN(Me)(CH2)2NMe2], the 1:1 complex 1-lithio-amido-3-(2-methylphenyl)isoquinoline-N,N,N′-trimethylethylenediamine (1-Li·HTriMEDA), has a solid-state structure which shows a new type of (NCNLi)2 core and a solution structure in which the coordination mode of the diamine by-product varies with temperature.
Type of Medium:
Electronic Resource
Permalink