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  • General Chemistry  (2)
  • 1965-1969  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    Entwicklungstendenzen bei der strahleninduzierten PolymerisationHerrn Professor K. Ziegler zum 70. Geburtstag gewidmet. (1968)
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 80 (1968), S. 921-932 
    Details
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Früher wurde allgemein angenommen, daß energiereiche Strahlung in Lösungen von Monomeren nur eine radikalische Polymerisation auszulösen vermag. Seit einiger Zeit sind jedoch strahleninduzierte Polymerisationen bekannt geworden, die über Ionen verlaufen. So kann man z. B. Lösungen eines Monomeren bei tiefer Temperatur, vorzugsweise in Gegenwart einer festen Substanz, ionisch polymerisieren. Überraschenderweise gelingt dies in ultrareinen, vor allem wasserfreien Systemen sogar bei Raumtemperatur. Die Natur der Ionen ist noch nicht völlig geklärt.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/ange.19680802202
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  • 2
    Electronic Resource
    Electronic Resource
    Trends in Radiation Polymerization (1968)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 7 (1968), S. 845-856 
    Details
    ISSN: 0570-0833
    Keywords: Polymerization ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Previously it was generally assumed that high energy radiation could only initiate radical polymerization in solutions of monomers. However, examples of radiation-induced polymerization have recently become known that proceed via an ionic mechanism. Thus, solutions of a monomer can be polymerized ionically, preferably in the presence of a solid, at low temperatures. Suprisingly, this may also be accomplished with ultra-pure, mainly anhydrous systems, even at room temperature. The nature of the ions has not yet been fully elucidated.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.196808451
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    Paper (German National Licenses)
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