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  • Africa  (1)
  • Gaseous hydrogen chloride  (1)
  • 1
    ISSN: 1573-0867
    Keywords: Africa ; biogenic emission ; dry season ; dynamic chamber ; forest ; grassland ; groundnut ; maize ; Miombo typesavanna ecosystem ; nitric oxide ; pulsing ; sorghum ; wet season ; Zimbabwe
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract During October to December 1994, we measured diel and seasonal variability in nitric oxide (NO) exchange by a southern African savanna ecosystem (Grasslands Research Station, Marondera, Zimbabwe). A set of automated dynamic chambers was installed in three sub-sites: Miombo forest, natural grassland, and cropped soils (maize, sorghum, groundnut). The latter received a single application of commercialy available in-organic or cowdung fertilizer. The dynamic chamber system is described in detail, including correction of the resulting data for wall losses and gas-phase reactions of the NO-NO2-O3 triad. During the dry season, net vertical NO fluxes were close to the detection limit (0.44 ngN m-2s-1) regardless of vegetation type. During the transition from dry to wet season strong "pulsing" effects of the NO flux were observed: NO emissions increased by a factor of up to 60 within hours. During the wet season, NO emissions varied between the different sub-sites of the ecosystem; corresponding means are in ranking order of fertilized agricultural plots (27.2 ngN m-2 s-1), unfertilized agricultural plots (8.5 ngN m-2 s-1 ), grassland (4.4 ngN m-2 s-1 ), and Miombo forest (1.5 ngN m-2 s-1). Soil moisture was found to be the dominant factor controlling the NO fluxes. Whenever it was not limiting, the diel behaviour of NO emission followed the daily variation of soil temperature measured 1 cm below the surface.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of atmospheric chemistry 2 (1984), S. 47-63 
    ISSN: 1573-0662
    Keywords: Gaseous hydrogen chloride ; tropospheric measurements ; vertical profiles ; marine and remote continental areas
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Vertical profiles of gaseous hydrogen chloride have been measured in the lower and middle troposphere. For sampling, denuder tubes coated with porous silica were used. Hydrogen chloride was determined by gas chromatography in combination with a derivatization method. The samples were collected over the Atlantic Ocean northwest of Norway in early September 1981 and over the Mediterranean Sea and north-eastern Spain in December 1981 at altitudes between 0.1 and 7 km. Above the 3 km altitude the mixing ratios are generally very low and relatively uniform with values of 50–100 ppt. Below 3 km, the variations of the HCl-mixing ratios are larger with maximum values of up to 500 ppt. The profiles are discussed with respect to the vertical and horizontal transport conditions and the possible sources and sinks of gaseous hydrogen chloride.
    Type of Medium: Electronic Resource
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