ISSN:
1612-1112
Keywords:
Gas-solid chromatography
;
Gas-adsorption chromatography
;
Henry's constants measurements, calculations
;
Aromatic, cyclic hydrocarbons
;
Chromatoscopy of tetralin
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Retention volumes at zero sample size (Henry's constants) on graphitized thermal carbon black have been measured at a number of temperatures for benzene, all its methyl-substituted and some of alkyl-substituted derivatives, naphthalene, diphenyl, phenanthrene, anthracene, tetralin, cis- and trans-decalin, cyclohexane, adamantane and diamantane. The earlier published thermodynamic characteristics of adsorption of the aromatic hydrocarbons have been revised. A molecular statistical calculation of thermodynamic characteristics of adsorption using the atom-atom approximation for the energy of intermolecular interaction between adsorbate and adsorbent has been carried out for polycyclic hydrocarbons: adamantane, diamantane, cis- and trans-decalin. The measured retention volumes of tetralin have been used for the calculation of some parameters of geometric structure of the molecule.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02260661
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