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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 35 (1993), S. 237-240 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Enantioselectivity ; Polysaccharide chiral stationary phase ; Amylose tris(n-butylcarbamate) ; Grob test
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Seven aromatic and alkyl amylose and cellulose carbamates have been tested as chiral stationary phases in gas chromatography. One of them, amylose tris(n-butylcarbamate) can be used for enantiomer separation.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 13 (1980), S. 263-270 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Metal complexes ; Enantiomers ; Isotopic composition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The high selectivity of complexation gas chromatography has been employed for enantiomer resolution and isotope separation. Thus, a chiral olefin, 3-methylcyclopentene, has been resolved analytically on optically active dicarbonyl-rhodium(I)-3-trifluoroacetyl-1R-camphorate in squalane. The deuterated ethylenes C2H4−nDn have been separated on the same rhodium(I)-containing stationary phase. The chiral aliphatic oxiranes epoxypropane andtrans-2,3-epoxybutane have been resolved on optically active nickel(II)-bis-3-trifluoroacetyl-1R-camphorate in squalane.
    Type of Medium: Electronic Resource
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