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  • 1
    Publication Date: 2011-08-19
    Description: A new cryogenic collection system has been flown on board a balloon gondola to obtain separate samples of ozone and carbon dioxide without entrapping major atmospheric gases. Precision laboratory isotopic analysis of CO2 samples collected between 26 and 35.5 km show a mass-independent enrichment in both O-17 and O-18 of about 11 per mil above tropospheric values. Ozone enrichment in its heavy isotopes was 9 to 16 percent in O3-50 and 8 to 11 percent in O3-49, respectively (Schueler et al., 1990). A mechanism to explain the isotope enrichment in CO2 has been recently proposed by Yung et al. (1991). The model is based on the isotope exchange between CO2 and O3 via O(1D), resulting in a transfer of the ozone isotope enrichment to carbon dioxide. Predicted enrichment and measured values agree well.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 18; 669-672
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  • 2
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    Publication Date: 2011-08-19
    Description: Mass spectrometer measurements of ozone made during two balloon flights included its heavy isotopes at mass 49 and 50. Both flights were flown during the day and during summer from Palestine, TX. At float altitudes above 42 km the enrichments in heavy ozone were 41 percent and 23 percent, respectively. The enrichment appears to be mass independent since, at high altitudes, both 49 and 50 show the same enhancement. During the descent the enrichment in heavy ozone decreased, faster during the first flight than during the second, reaching values between 15 and 20 percent above 30 km. Near and below this altitude another increase is observed. During a night flight, previously reported, an enhancement in heavy ozone of over 40 percent at 32 km was found, decreasing both toward higher and lower altitudes.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 14; 80-83
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  • 3
    Publication Date: 2011-08-19
    Description: The vapor pressure of ozone has been measured at liquid argon temperatures. At the normal boiling point of argon (-185.9 C) an ozone pressure of 0.0405 torr was obtained with an accuracy of + or - 1.5 percent. Increases and decreases in liquid argon temperatures raised and lowered the ozone vapor pressure, respectively. During the vapor pressure measurements the purity of ozone was monitored with a mass spectrometer. The proposed ozone standard will considerably improve the calibration of experiments for atmospheric research, the determination of absorption cross sections and other laboratory ozone studies.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 12; 89-92
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  • 4
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    Publication Date: 2011-08-18
    Description: The distribution of heavy ozone (molecular mass 50) has been measured for the first time in the stratosphere with a mass spectrometer system. During a balloon descent after midnight on September 4, 1980, a pronounced enhancement of heavy ozone was found. The maximum in the isotopic ratio, (O-18)(O-16)2/(O-16)3, occurred at 32 km where the enhancement of heavy ozone was over 40%. The ratio decreased toward higher and lower altitudes, and reached the standard value below 24 km. These measurements confirm an earlier prediction that there exists a preferred production mechanism for heavy ozone in the stratosphere.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters; 8; Aug. 198
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  • 5
    Publication Date: 2011-08-18
    Description: A mass spectrometer beam experiment and a UV absorption instrument (modified Dasibi instrument) have simultaneously measured ozone mixing ratios in the stratosphere (20-40 km). Both experiments were independently calibrated using absolute standards. The ozone profiles obtained during three balloon descents are in excellent agreement; fine structures are resolved by both experiments. The RMS uncertainty in ozone mixing ratios is about 3% for either instrument.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters; 8; Apr. 198
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  • 6
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    Publication Date: 2011-08-18
    Description: A mass spectrometer experiment for the analysis of minor constituents in the stratosphere has been flown successfully four times from Palestine, Texas on board a balloon gondola. The carbon dioxide mixing ratio, which shows unexpectedly large variations in the stratosphere, reached 400 ppm in one particular night flight. This is about 20% higher than the ground value. Evidence is presented that the experiment performed well during each of the balloon flights. The isotopic ratio C-12/C-13 was measured and found in good agreement with previous air analyses showing a depletion of C-13.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters; 7; Nov. 198
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  • 7
    Publication Date: 2011-08-19
    Description: Enrichment of heavy O3 isotopes has been measured in collected stratospheric samples. A balloon-borne cryogenic sampler was used to gather six O3 samples between 26 and 35 km in three flights. Subsequent laboratory mass spectrometer analysis of rare O3 isotopes at both mass 49 and 50 has resulted in more precise measurements than have previously been reported with in situ and ground-based techniques. In one flight, (O-50)3 was enriched by 12-16 percent and (O-49)3 by 9-11 percent, both increasing with altitude. In the remaining two flights, the isotope enrichment was nearly mass-independent at 8-9 percent. The enrichments in O3 at mass 50 are less than the large 40 percent value observed in some stratospheric measurements but similar to (O-49)3 and (O-50)3 fractionations produced in laboratory-generated ozone.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters (ISSN 0094-8276); 17; 1295-129
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  • 8
    Publication Date: 2019-06-28
    Description: Neutral composition data obtained by the open-source neutral-mass spectrometer on the polar orbiting Atmosphere Explorer D satellite during the periods October 31 to November 15, 1975, and January 5 to 15, 1976, are used to characterize the response of thermospheric atomic nitrogen densities to geomagnetic activity. These periods provided nearly simultaneous polar and low-latitude data coverage. At low and middle latitudes near dawn and at all latitudes on the dayside, N densities at 400 km appear to vary like those of a species of atomic mass 14: N is observed to increase with increasing geomagnetic activity in a manner similar to that of O. At auroral latitudes near dawn, however, there is a more complex dependence on the amplitude of the disturbance. For substorm-scale activity, N tends to increase during periods of auroral heating but exhibits a sharp temporary decrease afterward. During large storms there is a significant but short-lived increase of N at auroral latitudes. The present results support current models showing that N is produced and transported out of the auroral zone during geomagnetic disturbances.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 88; Aug. 1
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  • 9
    Publication Date: 2019-06-27
    Description: The open source neutral mass spectrometer on board the equatorial Atmosphere Explorer E satellite (AE-E) measured atomic nitrogen densities at frequent intervals during both the elliptical and circular orbit phases of satellite operations. Elliptical orbit data presented here by means of empirical models at 225- and 300-km altitude provide diurnal and seasonal profiles at altitudes lower than previously possible. Data from individual circular orbits later in the AE-E mission confirm essential features of these models, particularly the diurnal density profile. At lower altitudes, considerable variation is evident near midnight, with density enhancements correlated with increasing levels of geomagnetic activity.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research; 85; May 1
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  • 10
    Publication Date: 2019-06-27
    Description: The open-source neutral mass spectrometer (OSS) on the Atmosphere Explorer-C satellite (AE-C) measures the neutral constituents of the upper atmosphere. It has been found that atomic nitrogen densities can be determined at altitudes above 380 km. Most of the nitrogen atoms combine with oxygen adsorbed on the walls of the ion source to form NO. The measured net peaks at 14 amu and 30 amu show the scale height expected for atomic nitrogen; both peaks have a pronounced diurnal variation. Absolute number densities at 400 km are computed for a time period between February and April 1974 when measurements were taken in the northern hemisphere. Minimum and maximum densities of atomic nitrogen occur between 4 and 6 hr LST in the morning and around 16 hr LST in the afternoon, respectively. At 400 km, the minimum particle density is 100,000/cu cm and the maximum density 1.5 million/cu cm. In contrast to the response of N2 to geomagnetic activity, atomic N shows no appreciable effect.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters; 2; Aug. 197
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