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  • 1
    Publication Date: 2011-08-19
    Description: Absolute infrared line intensities of several ClO lines in the rotational-vibrational (1-0) band were measured using infrared heterodyne spectroscopy near 12 microns. A measurement technique using combined ultraviolet absorption and infrared line measurements near 9.5 microns and 12 microns permitted an accurate determination of the column densities of O3 and ClO in the absorption cell and thus improved ClO line intensities. Results indicate ClO line and band intensities approximately 2.4 times lower than previous experimental results. Effects of possible failure of local thermodynamic equilibrium conditions in the absorption cell and the implication of the results for stratospheric ClO measurements in the infrared are discussed.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 91; 2735-274
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  • 2
    Publication Date: 2011-08-17
    Description: Absolute line-center frequencies for eleven lines of ammonia in near coincidence with CO2-laser transitions have been determined to accuracies of + or -3 MHz by infrared heterodyne detection. These results were obtained by heterodyning a blackbody with a stable grating-tuned CO2 gas laser. A discussion of the apparatus and method of calculation, including error analysis, is presented. With these accurately determined line-center positions, the ammonia molecule will be a useful secondary-frequency standard for diode-laser spectroscopy in the 11-micron wavelength region.
    Keywords: LASERS AND MASERS
    Type: Optics Letters; 1; Sept
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  • 3
    Publication Date: 2011-08-17
    Description: Measurements of a stratospheric ozone concentration profile are made by detecting infrared absorption lines with a heterodyne spectrometer. The infrared spectrometer is based on a line-by-line tunable CO2 lasers, a liquid-nitrogen cooled HgCdTe photomixer, and a 64-channel spectral line receiver. The infrared radiation from the source is mixed with local-oscillator radiation. The difference frequency signal in a bandwidth above and below the local-oscillator frequency is detected. The intensity in each sideband is found by subtracting sideband contributions. It is found that absolute total column density is 0.32 plus or minus 0.02 cm-atm with a peak mixing ratio at about 24 km. The (7,1,6)-(7,1,7) O3 line center frequency is identified as 1043.1772/cm. Future work will involve a number of ozone absorption lines and measurements of diurnal variation. Completely resolved stratospheric lines may be inverted to yield concentration profiles of trace constituents and stratospheric gases.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters; 5; Apr. 197
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  • 4
    Publication Date: 2011-08-17
    Description: Intensity profiles of infrared spectral lines of stratospheric constituents can be fully resolved with a heterodyne spectrometer of sufficiently high resolution (approximately 5 MHz = 0.000167 kaysers at 10 microns). The constituents' vertical distributions can then be evaluated accurately by analytic inversion of the measured line profiles. Estimates of the detection sensitivity of a heterodyne receiver are given in terms of minimum detectable volume mixing ratios of stratospheric constituents, indicating a large number of minor constituents which can be studied. Stratospheric spectral line shapes and the resolution required to measure them are discussed in light of calculated synthetic line profiles for some stratospheric molecules in a model atmosphere. The inversion technique for evaluation of gas concentration profiles is briefly described, and applications to synthetic lines of O3, CO2, CH4, and N2O are given. Some recent heterodyne measurements of CO2 and O3 absorption lines are analytically inverted, and the vertical distributions of the two gases are determined.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research; 84; June 1
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  • 5
    Publication Date: 2011-08-17
    Description: A stratospheric ozone absorption line in the 10 micron band was measured and resolved completely, using an infrared heterodyne spectrometer with a spectral resolution of 5 MHz. The vertical concentration profile of stratospheric ozone was obtained through an analytical inversion of the measured spectra line profile. The absolute total column density was 0.32 plus or minus 0.02 cm-atm with a peak mixing ratio occurring at approximately 24 km. The (7,1,6) - (7,1,7) O3 line center frequency was found to be 1043.1772 plus or minus 0.00033 cm/1 or 420 plus or minus 10 MHz higher than the P(24) CO2 laser line frequency.
    Keywords: GEOPHYSICS
    Type: WMO Geophys. Aspects and Consequences of Changes in the Composition of the Stratosphere; p 99-101
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  • 6
    Publication Date: 2011-08-18
    Description: A ground-based search for stratospheric 35-ClO was carried out using an infrared heterodyne spectrometer in the solar absorption mode. Lines due to stratospheric HNO3 and tropospheric OCS were detected at about 0.2 percent absorptance levels, but the expected 0.1 percent lines of ClO in this same region were not seen. We find that stratospheric ClO is at least a factor of seven less abundant than is indicated by in situ measurements, and we set an upper limit of 2.3 x 10 to the 13th molecules/sq cm at the 95 percent confidence level for the integrated vertical column density of ClO. Our results imply that the release of chlorofluorocarbons may be significantly less important for the destruction of stratospheric ozone (O3) than is currently thought. Previously announced in STAR as N83-27518
    Keywords: GEOPHYSICS
    Type: Science (ISSN 0036-8075); 221; July 15
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  • 7
    Publication Date: 2016-06-07
    Description: The optical design considerations for optimization of sensitivity, tunability, and versatility of an infrared heterodyne spectrometer are discussed using the GSFC CO2 laser heterodyne spectrometer optical front end as an example. Problems related to the coherent nature of the laser local oscillator beam (e.g., interference effects at edges of optical elements and at the beam combining beamsplitter) are described and proper beamsplitter design discussed. Optimum matching to the telescope is discussed. The severe effects of large central obscuration on the coherent telescope efficiency are described and steps to partially recover the lost system sensitivity are proposed. Measurements made with the GSFC 48 inch telescope (linear obscuration rate = 0.5) and the KPNO McMathe telescope (no obscuration) are given as examples.
    Keywords: LASERS AND MASERS
    Type: NASA. Langley Res. Center Heterodyne Systems and Technol., Pt. 2; p 365-372
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  • 8
    Publication Date: 2016-06-07
    Description: A diode laser based IR heterodyne spectrometer for laboratory and field use was developed for high efficiency operation between 7.5 and 8.5 microns. The local oscillator is a PbSSe tunable diode laser kept continuously at operating temperatures of 12-60 K using a closed cycle cooler. The laser output frequency is controlled and stabilized using a high precision diode current supply, constant temperature controller, and a shock isolator mounted between the refrigerator cold tip and the diode mount. Single laser modes are selected by a grating placed in the local oscillator beam. The system employs reflecting optics throughout to minimize losses from internal reflection and absorption, and to eliminate chromatic effects. Spectral analysis of the diode laser output between 0 and 1 GHz reveals excess noise at many diode current settings, which limits the infrared spectral regions over which useful heterodyne operation can be achieved. System performance has been studied by making heterodyne measurements of etalon fringes and several Freon 13 (CF3Cl) absorption lines against a laboratory blackbody source. Preliminary field tests have also been performed using the Sun as a source.
    Keywords: LASERS AND MASERS
    Type: NASA. Langley Res. Center Heterodyne Systems and Technol., Pt. 1 p199-208 (SEE N80-29652 20-36)
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  • 9
    Publication Date: 2019-06-28
    Description: A ground based search for the 856.50137/cm R(9.5) and for the 859.76765 R(12.5) transitions of stratospheric (Cl-35)O was made in the solar absorption mode using an infrared heterodyne spectrometer. Lines due to stratospheric HNO3 and tropospheric OCS were detected, at about 0.3% absorption levels. The expected lines of ClO in this same region were not detected, even though the optical depth of the ClO lines should be on the order of 0.2% using currently accepted ClO abundances. These infrared measurements suggest that stratospheric ClO is at least a factor of 7 less abundant than is indicated by indirect in situ fluorescence measurements, and the upper limit of 2.4x10 to the 13th power molecules/sq cm to the integrated column density of ClO is a factor of over 4 less than is indicted by microwave measurements. Results imply that the release of fluorocarbon precursors of ClO may be significantly less important for the destruction of stratospheric ozone than was previously thought.
    Keywords: GEOPHYSICS
    Type: NASA-TM-83939 , NAS 1.15:83939
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  • 10
    Publication Date: 2019-06-28
    Description: Fully resolved intensity profiles of various lines in the CO2 bands at 9.4 micrometers and 10.4 micrometers were measured on Mars using an infrared heterodyne spectrometer. Analysis of the line shapes shows that the Mars atmosphere exhibits positive gain on these lines, providing the first definite detection of natural optical gain amplification and enabling identification of these lines as the first definite natural laser ever discovered.
    Keywords: LASERS AND MASERS
    Type: NASA-TM-82048
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