ISSN:
1434-193X
Keywords:
Cyclic voltammetry
;
Fullerenes
;
Phase-transfer catalysis
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Several pyrrolidinofullerenes were N-arylated by phase-transfer catalysis in the absence of solvent. The electrochemical behaviour of the novel C60-acceptor dyads was studied by cyclic voltammetry which showed that the nitro groups on the N-phenyl ring have a strong influence on the reduction potential values. Theoretical calculations at the semiempirical PM3 level fully support the experimental redox potential values.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
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