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  • 1
    ISSN: 1434-193X
    Keywords: Fullerenes ; Cubanes ; Atropisomerism ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: New dumb-bell-type fullerene adducts 2, 4, and 8a-b could be synthesized via bifunctional nitrile oxides. The [60]fullerene derivative 16 of this type was synthesized by twofold esterification with an isoxazolo[60]fullerenecarboxylic acid derivative. In the latter case the reaction was used to link the archimedic polyhedron fullerene with the platonic element cubane. When a bulky spacer between the fullerene units was used, atropisomeres 8a-b occurred. The fullerene derivative 11 with an anthracene moiety exhibited axial chirality.
    Type of Medium: Electronic Resource
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