ISSN:
1572-8927
Keywords:
Fluoride ion
;
solvation
;
transfer free energy
;
acidity parameters
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Linear free energy relationships between the free energy of transfer of fluoride ion from water to other solvents or solvent mixtures and each of several parameters describing the acidity of the solvent were found. The correlation is about of the same quality for the A parameter of Swain or the acceptor number, AN, and almost as good for the α parameter of Taft. The correlation was somewhat poorer with the E T (30) parameter.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00646612
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