ISSN:
0935-6304
Keywords:
Supercritical fluid chromatography, SFC
;
Flame ionization detector, FID
;
Metal selective detector
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
This work describes the construction and operation of a flame ionization detector for the selective detection of metal-containing compounds after capillary supercritical fluid chromatography. Using optimal conditions for achieving metal sensitive flame ionization responses which have been established for the detector after capillary gas chromatography, initial evaluation of the detector after SFC proved promising. Like the carbon sensitive FID, it appears that the metal sensitive FID is compatible with SFC when pure carbon dioxide is used as the mobile phase. Response characteristics were found to be similar to those observed when the detector is used in gas chromatography.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jhrc.1240110503
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