ISSN:
1588-2837
Keywords:
Fe(CN)5(4-tbupy)3-
;
kinetics
;
electrolytes
;
substitution
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The ligand substitution reaction [Fe(CN)5(4-tbupy)]3- + pyrazine (4-tbupy=4-tertbutylpyridine) was studied in aqueous concentrated electrolyte solutions at 298 K. Plots of ln(k/kw) against (γ-γw), where the subscript w refers to pure water and γ is the surface tension of the appropriate salt solution, gave a common straight line for all the electrolytes studied and permits to estimate the activation volume.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1010373823987
Permalink