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  • ErBa2Cu3O7  (2)
  • Industrial Chemistry  (1)
  • 1
    ISSN: 1572-9605
    Keywords: ErBa2Cu3O7 ; crystal growth ; microscopy ; superconductivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Millimeter-sized crystals of ErBa2Cu3O7 were fortuitously grown while sintering a flat disk. It was possible to separate individual crystals from the sintered mass and measure their properties. The resistive transition and onset of magnetic transition of a single crystal was 93 K and the resistive transition width was 〈 1 K. Flux expulsion was observed and individual crystals could be levitated by a magnetic field. Crystals showed unusual growth features. They were heavily corrugated along the part of the crystal that grew parallel to the top surface of the disk and that coincided with thec axis of the unit cell. Crystals were characterized by X-rays, electron microscopy, and optical microscopy.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1572-9605
    Keywords: ErBa2Cu3O7 ; superconductivity ; optical microscopy ; phase differentiation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract The orthorhombic superconducting phase of YBa2Cu3O7 is shown to be differentiable from its tetragonal precursor by optical microscopy. Individual grains 1 μm in diameter or larger are found to either exhibit the color of the compensator in reflected polarized light (tetragonal material) or to change colors from the compensator (orthorhombic material). By using color differences, retained tetragonal material and the orthorhombic nature of untwinned areas of grains are identified. The advantage to producing better superconducting single crystals and sintered polycrystalline materials is discussed.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 37 (1965), S. 639-643 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Es werden Messungen der Überspannung von Wasserstoff, Chlor und Sauerstoff an Graphit-Elektroden mitgeteilt. Die Überspannung des Wasserstoffs ist Durchtrittsüberspannung. Die Überspannung des Chlors ist vorwiegend Diffusionsüberspannung. Die Überspannung des Sauerstoffs aus wäßrigen Lösungen ist vorwiegend Konzentrationsüberspannung. Die Austauschstromdichten bei der Abscheidung von Wasserstoff sind sehr klein, dagegen bei der Abscheidung von Chlor und Sauerstoff sehr hoch. Die Überspannung des Sauerstoffs bei der Abscheidung aus geschmolzenen Salzen ist vorwiegend Reaktions- und Diffusionsüberspannung. Die Austauschstromdichte bezogen auf 1 Mol O2--Ionen pro Liter Schmelze beträgt 400 mA/cm2; der Durchtrittsfaktor ist 0,2.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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