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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Rheologica acta 36 (1997), S. 429-448 
    ISSN: 1435-1528
    Schlagwort(e): Extensional viscosity ; extensional flow ; elongational viscosity ; opposed nozzles ; extensional rheometry
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: Abstract Opposed-nozzle devices are widely used to try to measure the extensional viscosity of low-viscosity liquids. A thorough literature survey shows that there are still several unanswered questions on the relationship between the quantity measured in opposed-nozzle devices and the “true” extensional viscosity of the liquids. In addition to extensional stresses, opposed nozzle measurements are influenced by dynamic pressure, shear on the nozzles, and liquid inertia. Therefore the ratio of the apparent extensional viscosity that is measured to the shear viscosity that is independently measured is greater than three even for Newtonian liquids. The effect of inertia on the extensional measurements is analyzed by computer-aided solution of the Navier-Stokes system, and by experiments on low-viscosity Newtonian liquids (1 mPa s〈/ηS ⩽ 800 mPa s). The effect of nozzle separation-to-diameter ratio on the average residence time of the liquid is analyzed under the assumption of simple extensional flow kinematics. The average residence time of the liquid is independent of this ratio unless the radial inflow section of the extensional flow volume is related to the nozzle separation. Experiments indicate that in some cases widening the gap lowers the apparent extensional viscosity that is measured, whereas in other cases the opposite is true. In the light of these theoretical considerations and experimental observations, the use of systematic corrections to extensional viscosity measurements on non-Newtonian liquids is not recommended. Thus opposed nozzle devices should be considered as useful indexers rather than rheometers. Finally, measurements on a series of semi-dilute solutions of high molecular weight poly(ethylene oxide) in. water are also reported.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Rheologica acta 36 (1997), S. 429-448 
    ISSN: 1435-1528
    Schlagwort(e): Key words Extensional viscosity ; extensional flow ; elongational viscosity ; opposed nozzles ; extensional rheometry
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: Abstract Opposed-nozzle devices are widely used to try to measure the extensional viscosity of low-viscosity liquids. A thorough literature survey shows that there are still several unanswered questions on the relationship between the quantity measured in opposed-nozzle devices and the “true” extensional viscosity of the liquids. In addition to extensional stresses, opposed nozzle measurements are influenced by dynamic pressure, shear on the nozzles, and liquid inertia. Therefore the ratio of the apparent extensional viscosity that is measured to the shear viscosity that is independently measured is greater than three even for Newtonian liquids. The effect of inertia on the extensional measurements is analyzed by computer-aided solution of the Navier-Stokes system, and by experiments on low-viscosity Newtonian liquids (1mPas≤η S ≤800mPas). The effect of nozzle separation-to-diameter ratio on the average residence time of the liquid is analyzed under the assumption of simple extensional flow kinematics. The average residence time of the liquid is independent of this ratio unless the radial inflow section of the extensional flow volume is related to the nozzle separation. Experiments indicate that in some cases widening the gap lowers the apparent extensional viscosity that is measured, whereas in other cases the opposite is true. In the light of these theoretical considerations and experimental observations, the use of systematic corrections to extensional viscosity measurements on non-Newtonian liquids is not recommended. Thus opposed nozzle devices should be considered as useful indexers rather than rheometers. Finally, measurements on a series of semi-dilute solutions of high molecular weight poly(ethylene oxide) in water are also reported.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
  • 3
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 24 (1997), S. 813-831 
    ISSN: 0271-2091
    Schlagwort(e): pre-metered ; metered ; free boundary condition ; free surface flow ; viscous ; Engineering ; Numerical Methods and Modeling
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Notizen: In a forward-roll coating gap or nip, steady laminar flow of liquid between counter-rotating cylinders or rolls is used to split the flow into a coated layer on one roll and a rejected layer on the other. Both layers have free surfaces in contact with air. Liquid may be carried into the gap as a layer on one or both rolls. If the arriving layer is not too thick, all of the liquid flows through the gap, a situation called pre-metered. If the arriving layer is too thick, part of the liquid is rejected and runs back down the lower roll. The flow rate through the gap is said to be metered and is not known a priori.The transition from a pre-metered regime to the metered situation was examined by solving the Navier-Stokes system for steady, two-dimensional flow in a domain bounded by free surfaces, two rigid roll surfaces and chosen inflow and outflow surfaces. The free boundary condition, as described by Papanastasiou et al. (Int. j. numer methods fluids, 14, 587 (1992)), was explored and proved to accommodate both the pre-metered and metered regimes. A run-back flow state across the synthetic inlet plane was obtained, provided a condition on the thickness of the arriving layer was replaced by a kinematic condition at a certain stage.The coupled equation system was solved by Galerkin's method with finite element basis functions. The resulting non-linear algebraic system was solved by Newton's method with initialization by pseduo-arc-length continuation and automatic parameter step adjustment.Results show the existence of multiple solutions which can lead to hysteresis. Flow regime maps were constructed to portray the operating parameter range in which a coating bead can exist and the ranges in which a coating gap operates in either the pre-metered or the metering regime. © 1997 by John Wiley & Sons, Ltd. Int. j. numer. methods fluids 24: 813-831, 1997.
    Zusätzliches Material: 18 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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