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  • 1
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Ein Styrol/Maleinsäureanhydrid-Copolymeres (ST-co-MA), hergestellt aus Styrol und Maleinsäureanhydrid in Dimethylsulfoxid mit Azoisobutyronitril als Initiator, wurde durch eine Kondensationsreaktion auf Poly(vinylalkohol) (PVA) gepfropft. Die Strukturen der Produkte wurden mittels IR-Spektroskopie untersucht. Die Abhängigkeit der Pfropfterpolymerzusammensetzung, -viskosität und -ausbeute von der Konzentration der Reaktanden sowie die mechanischen Eigenschen von aus den Pfropfprodukten hergestellten Membranen wurden ermittelt. Bei der Untersuchung der Permeationseigenschaften zeigte sich, daß die Membranen bei allen Zusammensetzungen von Alkohol/Wasser-Gemischen bevorzugt für Wasser durchlässig sind. Mit steigendem PVA-Anteil in den Membranen und wachsendem Ethanolanteil der Alkohol/Wasser-Mischung nimmt die Durchlässigkeit ab und die Selektivität zu. Weiterhin wird der Einfluß der Größe der permeierenden Moleküle auf die Durchlässigkeit und Trenneigenschaften diskutiert.
    Notes: Graft copolymerization of styrene-maleic anhydride copolymer (ST-co-MA) onto poly(vinyl alcohol) (PVA) was carried out by a condensation-coupling reaction through esterification. The ST-co-MA copolymer was obtained by the copolymerization of MA and ST in dimethyl sulfoxide (DMSO), using azoisobutyronitrile as initiator. The structure of the reaction products was confirmed by infrared analysis. The dependence of composition, viscosity and yield of the graft terpolymers on the concentration of the reactants are presented in detail. Mechanical properties of membranes with different compositions were measured over a wide range of composition. It was found that water was permeated through the membranes preferentially in all ranges of feed compositions. The permeation decreased and the selectivity increased with increasing ethanol concentration in the feed and with increasing PVA content in the membrane. The effect of the molecular size of the permeating species on both permeation and separation is also discussed.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2019-08-13
    Description: Autonomous Underwater Vehicles (AUVs) are becoming increasingly important for military surveillance and mine detection. Most AUVs are battery powered and have limited lifetimes of a few days to a few weeks. This greatly limits the distance that AUVs can travel underwater. Using a series of submerged AUV charging stations, AUVs could travel a limited distance to the next charging station, recharge its batteries, and continue to the next charging station, thus traveling great distances in a relatively short time, similar to the Old West Pony Express. One solution is to use temperature differences at various depths in the ocean to produce electricity, which is then stored in a submerged battery. It is preferred to have the upper buoy submerged a reasonable distance below the surface, so as not to be seen from above and not to be inadvertently destroyed by storms or ocean going vessels. In a previous invention, a phase change material (PCM) is melted (expanded) at warm temperatures, for example, 15 C, and frozen (contracted) at cooler temperatures, for example, 8 C. Tubes containing the PCM, which could be paraffin such as pentadecane, would be inserted into a container filled with hydraulic oil. When the PCM is melted (expanded), it pushes the oil out into a container that is pressurized to about 3,000 psi (approx equals 20.7 MPa). When a valve is opened, the high-pressure oil passes through a hydraulic motor, which turns a generator and charges a battery. The low-pressure oil is finally reabsorbed into the PCM canister when the PCM tubes are frozen (contracted). Some of the electricity produced could be used to control an external bladder or a motor to the tether line, such that depth cycling is continued for a very long period of time. Alternatively, after the electricity is generated by the hydraulic motor, the exiting low-pressure oil from the hydraulic motor could be vented directly to an external bladder on the AUV, such that filling of the bladder causes the AUV to rise, and emptying of the bladder allows the AUV to descend. This type of direct buoyancy control is much more energy efficient than using electrical pumps in that the inefficiencies of converting thermal energy to electrical energy to mechanical energy is avoided. AUV charging stations have been developed that use electricity produced by waves on floating buoys and that use electricity from solar photovoltaics on floating buoys. This is the first device that has absolutely no floating or visible parts, and is thus impervious to storms, inadvertent ocean vessel collisions, or enemy sabotage.
    Keywords: Energy Production and Conversion
    Type: NPO-46985 , NASA Tech Briefs, January 2014; 8-9
    Format: application/pdf
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  • 3
    Publication Date: 2019-08-24
    Description: An energy producing device, for example a submersible vehicle for descending or ascending to different depths within water or ocean, is disclosed. The vehicle comprises a temperature-responsive material to which a hydraulic fluid is associated. A pressurized storage compartment stores the fluid as soon as the temperature-responsive material changes density. The storage compartment is connected with a hydraulic motor, and a valve allows fluid passage from the storage compartment to the hydraulic motor. An energy storage component, e.g. a battery, is connected with the hydraulic motor and is charged by the hydraulic motor when the hydraulic fluid passes through the hydraulic motor. Upon passage in the hydraulic motor, the fluid is stored in a further storage compartment and is then sent back to the area of the temperature-responsive material.
    Keywords: Energy Production and Conversion
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  • 4
    Publication Date: 2019-08-26
    Description: An energy producing device, for example a submersible vehicle for descending or ascending to different depths within water or ocean, is disclosed. The vehicle comprises a temperature-responsive material to which a hydraulic fluid is associated. A pressurized storage compartment stores the fluid as soon as the temperature-responsive material changes density. The storage compartment is connected with a hydraulic motor, and a valve allows fluid passage from the storage compartment to the hydraulic motor. An energy storage component, e.g. a battery, is connected with the hydraulic motor and is charged by the hydraulic motor when the hydraulic fluid passes through the hydraulic motor. Upon passage in the hydraulic motor, the fluid is stored in a further storage compartment and is then sent back to the area of the temperature-responsive material.
    Keywords: Energy Production and Conversion
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  • 5
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    In:  CASI
    Publication Date: 2019-08-26
    Description: A power generation system includes a plurality of submerged mechanical devices. Each device includes a pump that can be powered, in operation, by mechanical energy to output a pressurized output liquid flow in a conduit. Main output conduits are connected with the device conduits to combine pressurized output flows output from the submerged mechanical devices into a lower number of pressurized flows. These flows are delivered to a location remote of the submerged mechanical devices for power generation.
    Keywords: Energy Production and Conversion
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