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  • Enantioselectivity  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    General Aspects and Optimization of Enantioselective Biocatalysis in Organic Solvents: The Use of Lipases [New Synthetic Methods (76)] (1989)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 28 (1989), S. 695-707 
    Details
    ISSN: 0570-0833
    Keywords: Enantioselectivity ; Lipases ; Synthetic methods ; Enzyme catalysis ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Enantioselective biocatalysis in nonaqueous media is becoming increasingly important in preparative synthetic chemistry. This article discusses (1) the general catalytic properties of enzymes in nonaqueous environments, (2) the basic principles that govern lipase-catalyzed enantioselective esterification and transesterification reactions in organic media for the preparation of optically active acids and alcohols, (3) the determination of kinetic and thermodynamic parameters, and (4) the quantitative analysis of published data.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.198906951
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Microbial Asymmetric Catalysis - Enantioselective Reduction of Ketones [New Synthetic Methods (45)] (1984)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 23 (1984), S. 570-578 
    Details
    ISSN: 0570-0833
    Keywords: Asymmetric catalysis ; Catalysis ; Enantioselectivity ; Reduction ; Ketones ; Synthetic methods ; Biotechnology ; Alcohols ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Microbial asymmetric reduction of ketones is a method widely used for the preparation of chiral alcohols. The present progress report deals with the basic concepts that govern enantioselectivity of enzymes and intact cells. Strategies to control the stereochemical course of microbial reductions of carbonyl compounds and the relationship of substrate structure to enantioselectivity are considered.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.198405701
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    Paper (German National Licenses)
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